微波法合成N,N′-二哌啶基硫脲及表征.pdfVIP

印染助剂 Vol.30 No.2 第30卷第2期 2013 年2 月 TEXTILE AUXIUARIES Feb.2013 微波法台成N.N-二眼睫摹硫服及表征 孙宾涛，郭睿，赵鹏飞，宋军旺 (陕西科技大学教育部轻化工助剂化学与技术重点实验室，陕西西安 71∞21) 摘 要:以硫服的无7.1乙醇酒波和六氢毗脏为原剿，在无催化刑的辐射作用下，探索制备N，N-二眼眶墨硫朦的工艺条件，并 对真结何进行了袤征.通过正巫试验得出最佳的合成工艺条件:在微波仪噩噩-时闰匠E模式下，硫靡的无7.1乙酵酒液质量分数为 1.56%月(硫服):n(六氢毗脏:}=I :2.2，搅伴速度5∞r/min，55 c辐射KS19min，收率可达65.78%. 关键词: 微波法;抗臭氧刑; N，N-二服院墓硫服;六氢毗院;正交试验 中图分类号: TQ245.28 文献标识码: A 文章编号: 1004斗439(2013问2-0027-03 Syn世lesis and characteriza咀on of N ,N -di-piperidi-l-thiourea under microwave irradia咀on SUN Bin-归。， GUO Rui, ZHAO R回tg-fei， SONG Jun-wαη。 (Key Laboratory of Auxiliary Chemistry Technology for Chemical Industry, Ministry of Education, Shaanxi University of Science Technology, Xian 71∞21， China) Abs仕act: Di-piperidin-1-thiourea was synthesized with ethanol solution of thiourea and hexahydropyri- dine in the absence of catalyst and microwave irradiation, and the structure of the product was characterized. The optimal experimental conditions were found through the orthogonal experiments: in the temperature-time response mode of microwave irradiation, ethanol solution of thiourea was 1.56% , n(thiourea): n(hexahydropyri- dine)=1: 2.2, stirring speed was 500 r/min , reacted at 55 c for 9 min. Under the optimal condition , the yield could reach 65.78%. Key words: microwave irradiation; anti-ozone agents; N,N-di-piperidin-1-thiourea; hexahydropyridine; orthogonal experiment 硫服衍生物防老剂具有防臭氧老化、防氧化和 物的供电子能力，从而增加其抗臭氧能力 [4]经正交试 改进动态疲劳性能的特点.其最大特征是非污染性和 验，探讨了最优的合成工艺条件. 低着色性，且