微米级PS-PEDOT核壳型导电微球的合成与拉曼表征.pdfVIP

Vo l. 27 No.3 功能高分子学报 272 Journal of Functional Polymers 2014 年 9 月 微米级 PS-PEDOT 核壳型导电微球的合成与拉曼表征 王 普1 ， 李郭成1 ， 邓兆静1 ， 高康莉1 ， 韩国志1.2 (1.南京工业大学理学院，南京 210009; 2. 东南大学生物电子学国家重点实验室，南京 210096) 摘 要: 以分散聚合法制备的微米级聚苯乙烯(PS) 微球为模板、3 ， 4- 乙烯二氧嚷吩(EDOT) 为 单体、过硫酸是安(APS) 为引发剂，通过氧化聚合制备了 PS-PEDOT 核壳型复合导电微球。采用扫 描电镜、透射电镜等对导电微球的形貌和结构进行了表征，重点采用拉曼光谱研究了其核壳结构特 征。并研究了超声分散、溶液 pH 以及单体配比对导电微球形貌的影响。实验结果表明:超声的引 入可提高导电微球的单分散性，改善微球的形貌。随着 pH 的降低或单体配比的增加，导电聚合物 在 PS 微球表面的负载量随之增加，当 m(EDOT)/m(PS) 由 O. 60 增加到1. 25 时，导电微球的平均 粒径由1. 76μm 增加到1. 91μm。 关键词: 微米级;聚苯乙烯;EDOT; 导电微球;拉曼表征 中图分类号: 063 文献标志码: A 文章编号: 1008-9357(2014)03-0272-06 Preparation and Raman Characterization of Micron-Sized Core-Shell PS-PEDOT Conductive Microspheres WANG Pu l , LI Guo-chengl , DENG Zhao-jingl , GAO Kang-li l , HAN Guo-zhi l. 2 (1. College of Science , Nanjing Tech UnÎversity , Nanjing 210009 , China; 2. State Key Laboratory of Bioelectronics , Southeast University , Nanjing 210096 , China) Abstract: Using monodispersed micron-sized PS microspheres as template , EDOT as monomer and APS as initiator , the core-shell PS-PEDOT conductive microspheres were synthesized by chemical oxidation polymerization. The morphology and structure of PS-PEDOT were characterized by SEM and TEM. The characteristic of core-shell structure of PS-PEDOT microspheres was emphatically studied by Raman spec- tra. On the basis , some synthesis conditions such as ultrasonic irradiation , pH value of PS emulsion and monomer ratio were optimized. Results indicated that ultrasonic could improve the m