微波改造沸石环境材料的表征与脱氮效果.pdfVIP

Vo 1. 36 ,No.l 东北大学学报(自然科学版) 第 36 卷第 1 期 Joumal of Northeastem University( Natural Science) Jan. 2015 2015 年 1 月 doi: 10. 3969/j. issn. 1 ∞5 - 3026.2015.0 1. 028 微波改造沸石环境材料的表征与脱氮效果 林海，杨苏，张文通，马麟钧 (北京科技大学土木与环境工程学院，北京 1 ∞083 ) 摘 要:通过添加不同类型助剂对天然沸石进行微波改造制备环境材料，并研究其对再生水中氨氮的去 除效果.研究发现，相同的改造条件下，不同助剂的微波沸石对氨氮的去除效果顺序为:乙酸铀微波沸石〉 NaCI 微波沸石 SDS 微波沸石 CTMAB 微波沸石〉单独微波沸石〉原沸石.孔径测试结果显示微波沸石 的总孔体积、孔径数量、比表面积均有所提高.通过 SEM， XRD 等于段对微波改造前后的沸石表征，微波改造 过程中助剂的加入使沸石颗粒表面松散度有不同程度的提高，出现了更多的孔道，主衍射峰强度有所减弱，沸 石吸附性能提高. 关键词:沸石;氨氮;微波改造;助剂;再生水处理 中图分类号: X 703.5 文献标志码:A 文章编号: 1005 -3026(2015)01 -0129 -05 Characterization and Denitriding EfTect of Microwave Modified Zeolite Ecomaterials LIN Hα， i ， YANG Su , ZHANG Wen-tong , MA Qi-jun (School of Civil and Environmental Engineering , University of Science and Technology Beijing , Beijing 1α)()83 ， China , Corresponding author: LIN H缸， E-mail: linhai@ces.ustb.edu.cn ) Abstract: Ecomaterials were modified and prepared by adding different additives on natural zeolite with rnicrowave , and the effect of the matrials on removal of arnmonia nitrogen was investigated. The results showed that the removal effect of arnmonia nitrogen in sequence under the s缸ne modification conditions is rnicrowave-assisted zeolite with sodium acetate , rnicrowave- assisted zeolite with NaCl , rnicrowave-assisted zeolite with SDS , rnicrowave-assisted zeolite with CTMAB , rnicrowave-assisted zeolite and natural zeolite. The aperture , pore volume and BET surface area increased after rnicrowave-assisted zeolite with additives. The results of surface characteristics of zeolite were modificated with rnicrowave or wit