2习题 第二章 热力学第二定律（国外英文资料）.doc

2习题 第二章 热力学第二定律（国外英文资料） The second law of thermodynamics A multiple choice. The following description of the carnot cycle is correct () The a. carnot cycle is complete, the system is restored, the environment cannot be restored, it is an irreversible cycle When the b. carnot cycle is complete, the system is restored, the environment cannot be restored, it is a reversible cycle The C carnot cycle is complete, the system is restored, the environment is restored, it is irreversible The d. carnot cycle is complete, the system is restored, the environment is restored, it is a reversible cycle The carnot engine, which works in the two large reservoirs of 393K and 293K, is about () efficient. A. 83% b. 25% c. 25% d. 20% 3, for isothermal compression process of ideal gas, (1), (2) Q = - W Δ U = Δ H, (3) Δ S = 0, (4) Δ S 0, (5) Δ S 0 of the five relations, is not correct () (1) (2) (2) (2) (1) (2) (2) (2) (2) (2) (1) (2) (1) (2) (1) (2) (1) (2) (1) (2) (1) (2) (1) (2) (2) ( 4, set Δ S1 and Δ S2 respectively for n molO2 (as qi), by the constant pressure and constant volume process, the entropy change of temperature from T to 2 T, Δ S1 / Δ S2 equals () A. 5/3 b. 5/7 c. 7/5 d. 3/5 In the irreversible cycle, the entropy variable of the system () A. greater than zero c. less than zero c. is zero d. not sure 6, the free expansion process of ideal gas, (1) Q = Δ H, (2) Δ H Q, (3) Δ S = 0 0, (4) Δ S. Of the four relationships, the correct one is () (2) (3) (3) (3) (1) (3) (1) (3) (1) (3) (1) (3) (1) (3) (1) (3) (1) (3) (1) (3) (1) (3) (1) (3) (1) ( 7, 1 mole of the ideal gas from 300K, 1 times 106Pa adiabatic expansion to 1 x 105Pa, the process (). A. Δ S 0, Δ G Δ a. b. Δ S 0, Δ G Δ A C. Δ S = 0, Δ G = Δ a. d. Δ A = 0, Δ G Δ A An isolated system happens spontaneously, and () A. Δ A 0 B. Δ A = 0 c. Δ A 0 D. Δ A symbol cannot be determined 9, the following Δ G = 0 process is in the process of () A. adiabatic reversible and Wf = 0 The reversible process of the Wf = 0 C. Isot