铅模板交联壳聚糖聚合物的表征及吸附选择性研究.pdfVIP

张名楠等铅横板交联壳聚糖聚合物的衰征及暖附选择性研究 铅模板交联壳聚糖聚合物的表征及吸附选择性研究* 张名楠 于文辉 粱振益 (海南大学材料与化工学院，海南 海口570228) 摘要 变差；利用分子印迹技术得到的MIP呈具有一定孔径分布的多孔结构，这有利于Pb2+的吸附和洗脱，也为Pb2+的扩散或洗脱提供 了良好的通道；MIP在实际水样处理中体现出较高的Pb2+吸附选择性，它在处理含Pb2+废水方面可能具有较好的应用前景． 关键词 交联壳聚糖分子印迹聚合物Pb2+选择性 Cha嗽tel血ati蚰of ZHANG sel∞tMty C^册lic口Z ^靠挖g撇以，Ⅵ，W≥砌谢，L队NGZ^e行∥．(CDZZegeD，Ma￡e砌f彻d E竹gi埘eri挖g，H口i柏nUhi埘rsi缈， H口i忌。甜fini舱竹570228) Abst穗ct： andPb2+cross_linkedchitos锄molecularim— CT孓Pb2+compound，(丌孓Pb2+cross-linkedpoiymer withPb2+as numeratorandchitosan(CTS)asfunctionalmonomer． printedpolymer(MIP)wassynthetized template Thestructureandsurface of andMIPwas app∞ranceCTS，CT§Pb2+compound，CT孓Pb2+crosS-linkedpolymer characterizedInfrared the瑚al electron d主ffraction by spectrum。 amlysis，scanning micros∞py(SEM)and妊弛y (XRD)instrument．TheresultsshowedthatPb2+wasadsorbed of structureand mainly on—NH2CTS，the prope卜 tiesofCTSwas after Pb2+．The andthemal ofPb2+adsorbedCTS markedIychar蟮edadsorbing crystallinity stabi“ty was decreased withrawCTS．TheMIP showed obviously compared preparedbymolecularlyimprintedtechnology structurewithcertain of sizedistribution．This structuralcharacteristicswasbeneficialfor porous rangepore unique and elutionofPb2+，italsoofferedessentialchannelsforthediffusionandelutionofPb2+．MIP adsorption