无金属ATRP.pptxVIP

Metal-Free Atom Transfer Radical Polymerization（无金属ATRP);Controlled free radical polymerizations (CRPs)： metal catalyst ——metal contamination photomediated ATRP of methacrylates and acrylates using Ir-based photoredox catalysts organic-based catalyst that could replace Ir(ppy)3; ; Reaction conditions: MMA , photocatalyst ,1,DMA at room temperature with irradiation from 380 nm for 4 h 1、10-methyl phenothiazine (Me-PTH) poor control over the PDI 2-6、(b Reaction run with benzyl methacrylate for 7 h) Mn ~the initial monomer/initiator ratio low PDI c Run in the dark. d Run in the absence of 1. e Run in the absence of catalyst. indeed a photomediated process that is initiated by 1 and catalyzed by PTH f Irradiated with visible. oxidizing in the excited state, no reaction occurred;;;chain-end fidelity（活性链端的保留度）;block copolymerization provides definitive proof ：controlled polymerization system （PTH ） give a starting PMMA homopolymer as macroinitiator alkyl bromide chain-end fidelity， high reinitiation efficiency combining metal-free ATRP with other controlled radical processes;谢 谢 ！