溶解热的测定(国外英文资料).docVIP

溶解热的测定(国外英文资料) Determination of heat of solution [application] pharmaceutical, pharmaceutical preparations, Chinese pharmacy, pharmaceutical engineering, Chinese medicine (International Exchange), biological engineering [class hour] 3 hours First, the purpose of the experiment 1, the heat of dissolution of KNO3 in water was measured by calorimetry. 2. Grasp the basic principle and method of measuring temperature and heat. 3. Understand the basic principle of calorimetry for determining integral heat of solution. Two 、 experimental principle The dissolution of a substance is often accompanied by a heat effect, which is called the heat of dissolution of the substance. The heat of dissolved matter usually involves the destruction of the lattice of solutes and solvation of solute molecules or ions. Among them, the destruction of the lattice is often endothermic process, solvation is often exothermic process, dissolved heat is the sum of the total heat of these two processes. In the end, heat absorption or heat release is determined by the relative size of the two heat. Temperature, pressure, and the nature of the solute and solvent dosage, significantly affected the dissolution heat, according to the change of the concentration of substances in solution dissolved in the process of dissolving heat is divided into thick and thick set dissolved solution heat, thicken the heat of solution also called integral heat of solution, for constant temperature and constant pressure under one mole of a substance dissolved in a certain amount of solvent to form a solution concentration, absorbing or releasing heat, strong heat of solution is also called fixed differential dissolution heat, for constant temperature and constant pressure under the condition of one mole of a substance dissolved in a certain concentration of the solution, the heat generated by the. Integral heat of dissolution calorimetry can be directly measured, differential heat of solution from the integral heat of so