镍硼合金化学分析方法(国外英语资料).docVIP

镍硼合金化学分析方法(国外英文资料) Determination of boron content by acid base titration 1 range This standard specifies the method for the determination of boron content by acid-base titration, the summary, the actual materials, the apparatus and equipment, the analysis procedure and the calculation of the analysis results. For the determination of boron in nickel boron alloy, determination range (mass fraction): = 1%. 2 method summary The sample is fused by sodium peroxide, water leaching, dry filtration and separation of iron, manganese and nickel etc.. Separation of aluminium by calcium carbonate. The filtrate with methyl red to neutral, in the presence of mannitol, using phenolphthalein as indicator, titrate with sodium hydroxide standard solution. The mass fraction of boron is calculated according to the consumption of the standard solution. 3 reagent 3.1 sodium peroxide (solid) 3.2 calcium carbonate (solid) 3.3 mannitol (solid) 3.4 hydrochloric acid (1+1) 3.5 hydrogen peroxide (1.10g/mL) 3.6 barium chloride solution (300g/L) 3.7 phenolphthalein solution (10g/L) to take 1g of phenolphthalein, soluble in ethanol (3+2) in 100mL. 3.8 methyl red solution (5g/L) 3.9 sodium hydroxide standard solution (0.0741mol/L) Preparation of 3.9.1 sodium hydroxide standard solution Take 40g of sodium hydroxide, dissolved in 250mL water, add 10mL of barium chloride (3.6) - 3min 2min, boil slightly cold, dilute with water to 1000mL, mixing, static, the precipitation of barium carbonate after the sinking, the supernatant solution of siphon to another bottle, after the use of calibration. Calibration of 3.9.2 sodium hydroxide standard solution 0.3000g said benchmark phthalate in 105 drying two potassium hydrogen phthalate three, were placed in a 250mL conical flask, adding 20mL ethanol solution, add 50mL drops of neutral water, 2 - (3.7) 3 drops of phenolphthalein solution with sodium hydroxide standard solution (3.9.1) titration until the solution is slightly red for the end point. Take its avera