固相微萃取-气相色谱法测定洗涤制品中二噁烷.pdfVIP

第33卷第4期 黑龙江环境通报 V01．33No．4 2009 EnvironmentalJournal Dec 2009年12月 Heilongjiang 固相微萃取一气相色谱法测定洗涤制品中二嗯烷 韩丽媛 黄湘琪(齐齐哈尔市环境监测中心站 黑龙江 齐齐哈尔 161005) 摘要：本文采用顶空一固相微萃取一毛细管气相色谱联用技术测定了洗涤制品中二嚏烷量，使用50p．mPEG／树脂萃 X0．32ram 取头。顶空平衡温度为80℃，萃取时间为40rain。使用石英毛细管柱：30m X0．41xmi．也内壁涂有5％二苯基 102％。 关键词：顶空固相微萃取；气相色谱；洗涤制品；1，4二睫烷 中图分类号：X853 文献标识码：A 文章编号：1674—263X(2009)04—0023—03 Determinationof in ChemicalsSPME—Gas 1，4一dioxane Detergent by Chromatography HAN HUANG Li—yuan Xiang—qi Centerof (EnvironmentalMonitoringQiqihar，Qiqiharl61005) this wasusedtodetdrmine In Abstract：In 1，4一dioxane paper，headspace—SPME—gaschromatography Deter Chemicals．ThePEG／risinfiberwasmadeSPMEextraction bottle gents 501xm coating．Theheadspace was inawaterbathat timewas40rain．30mX i．d．GC eolum put 80℃．Absorption 0．32mm×0．4p．mcapillary with as was standardmethod 5％diphenylgroup(95％)polysiloxanexseriesstationaryphaseu．sed．Extenal was for the of0．35 60 wereall linear be- used quantitation．Inrange 1ag／g一11xg／g，there good relationships tweentheconcentrationandtherelativeareasofacetoneand corrlation peak isopropanol，the was0．9998．therelativestandarddeviationwas9．33andtherecoverieswere98．7％一102％． Keywords：HS—SPME；GasChromatography；DetergentChemical；1，4一dioxane