纤维素是自然界存在最丰富的多醣类,且可应用於-宜兰大学食品科学系.docVIP

國立宜蘭大學食品科學系碩士班專題討論 題目：磨對纖維素影響Effect of ball milling on microstructure of degraded cellulose 研究生專題討論書面摘要 指導教授：陳輝煌 老師 報 告 者：陳束筠 報告日期：2007/1/07 球磨對纖維素影響 摘要 降解纖維素使其粒徑下降提高表面積，可促進化學反應的進行，水溶性纖維素或寡糖聚合物，對人類的健康有很大的助益，因此本報告將介紹研磨對纖維素降解的影響。纖維素具有高度結晶，使纖維素不定形。未經處理纖維素，分子內和分子間OH基氫鍵結在一起，因此只有一小部份的OH基在纖維素表面和其它物質反應，纖維素球OH基拉伸振動波3500 cm-1)的波峰變寬，顯示纖維素結晶度減少或聚合度降低，此乃氫鍵破壞，造成纖維素微大量自由OH基，提高界面化學反應，形成新的復合材料晶纖維素(MCC)，的球磨條件為原料2、球珠尺寸12、頻率18 HZ，球磨溫度對MCC粒似無顯著影響，MCC從球珠得到壓力後提供破碎能量，導致較大的球珠尺寸對降低MCC的粒徑更有效率。 關鍵字：球磨、Abstract Degradation of cellulose not only reduced the particle size but also increased its surface area and thus enhanced chemical reactions. Both of the water soluble cellulose and oligomers obtained in milling process exhibit a great deal of benefit to human health. The effect of milling on degradation and structure influence of cellulose will be introduced in this report. Cellulose is a very high crystalline polymer. After mechanical ball milling was performed in a planetary ball mill, the X-ray diffraction intensities of cellulose crystal decrease as milling time increase. The milling caused a marked decrease in the crystallinity, making the cellulose highly amorphous. In native cellulose, almost of the OH groups were bound to one another through intra- and inter-molecular H-bonds. Only a small number of the OH groups on the surface could react with other substances. The OH-stretching vibration region (3200 to 3500 cm-1) became broader in the FTIR spectra and is mainly associated with a decrease in the degree of crystallinity and/or polymerisation of the milled cellulose. The collapse of the inherent hydrogen bonds yields a great number of free OH groups on the resultant cellulose microparticles, which may have enhanced interfacial chemical reactions and then forms the new composite. The desirable operating conditions on the wet milling of microcrystalline cellulose (MCC) with Retsch Mixer Mill was 2 g of material using 12 mm ball and a frequency of 18 HZ. Milling temperature seems to h