环氧大豆油的界面催化氧化合成研究.pdf

Subject : InterfacialCatalyticOxidative Synthesisof Subject : InterfacialCatalyticOxidative Synthesisof SSuubbjjeecctt ::IInntteerrffaacciiaallCCaattaallyyttiiccOOxxiiddaattiivvee SSyynntthheessiissooff EpoxySoybeanOil EpoxySoybeanOil EEppooxxyySSooyybbeeaannOOiill Specialty : ChemicalTechnology (Signature) Specialty : ChemicalTechnology (Signature) SSppeecciiaallttyy ::CChheemmiiccaallTTeecchhnnoollooggyy ((SSiiggnnaattuurree)) Name :Sha Wei Name :Sha Wei NNaammee ::SShhaa WWeeii Instructor :Yong-JunHe (Signature) Instructor :Yong-JunHe (Signature) IInnssttrruuccttoorr ::YYoonngg--JJuunnHHee ((SSiiggnnaattuurree)) ABSTRACT ABSTRACT AABBSSTTRRAACCTT Epoxy Soybean Oil(ESO) as environmental,biologic degradative and steady plasticizer is an internationally recognized green plasticizing agent.ESO is a promising plasticizer for PVC,due to its good compatibility,light and heat stability, low volatile and migratory.Meanwhile it also has non-toxic and good stability for the food and pharmaceutical packaging materials. At present,ESO is produced by a non-solvent route with hydrogen peroxide as oxidant and formic acid or acetic acid as catalyst.This route has disadvantages such as the low reaction stability and epoxy value of products, deep color of products, equipment corrosion and environmental pollution. Here，we report a new interfacial catalytic synthesis method for preparing ESO by using hydrogen peroxide as an oxidant and solid catalyst. This route has advantages such as the simple reprocessing,just washing can separ