固相法及燃烧法合成Y2MoO6Eu3荧光粉及荧光性能研究.docx

固相法及燃烧法合成Y2MoO6:Eu3+荧光粉及荧光性能研究摘要荧光粉的合成方法对其性能有很大影响，适当的合成方法可以有效的提高荧光粉的性能。传统的固相法合成的荧光粉性能优秀，不过也存在一定的不足，如：反应的温度相当的高，制备需要的时间也非常的长，能耗相对来说也不低等，在一定程度上增加了制备的成本。相对而言，燃烧法的合成温度较低，反应时间较短，在一定程度上弥补了固相法的缺点。因此，本文选取Y2MoO6为基质材料，通过掺杂Eu3+离子合成具有红色荧光的荧光粉。采用燃烧法和传统的固相法进行对比，研究了不同合成方法对其荧光性能的研究。并通过TG-DSC﹑DRX﹑SEM扫描电镜﹑激发发射光谱等表征方法来对我们制备的物质的结构、形状样貌还有光谱特征做了一系列的实验探究和学习。通过对测试结果分析可知，两种方法均可制备出具有纯相的Y2MoO6:Eu3+荧光粉。通过对荧光光谱分析可知，固相法合成的样品在1000℃下具有最高的荧光发射；而燃烧法合成的样品在1100℃下表现出最好的荧光性能。关键词：结晶性；燃烧法；固相法；Y2MoO6:Eu3+；荧光性能。Abstract?The?way?of?compounding?phosphor?has?a?major?impact?on?its?performance,?which?can?be?improved?by?some?proper?synthetic?ways.?It?can?not?be?denied?that?traditional?Solid-phase?method?makes?the?performance?of?phosphor?excellent.?However,?it?needs?a?higher?compounding?temperature,?longer?reaction?time?as?well?as?higher?energy?consumption,?which?adds?up?the?cost?of?production?to?some?extent.?Comparativrly?speaking,?Combustion?method?has?several?advantages?that?can?make?up?for?the?Solid-phase?method.?Such?as?lower?compounding?temperature?and?shorter?reaction?time.?Thus,?this?passage?choose??as?a?basic?material,?adding??to?compound?the?phosphor?with?red?fluorescent.?There?is?a?comparison?between?the?Combustion?method?and?traditional?Solid-phase?method,?which?meets?our?needs?to?study?how?performance?can?be?impacted?by?different?synthetic?ways.?What’s?more,?we?are?able?to?study?and?analyze?the?phase?structure,?the?shape?as?well?as?the?spectral?properties?of?the?synthetic?material?systematically.?The?characterization?methods?to?study?and?analyze?the?phase?structure??like?scanning?electron?microscope?and?stimulating?emission?spectrum?such?as?TG-DSC,?DRX?and?SEM?are?available.?Through?analyzing?the?result?of?the?test,?it?can?be?concluded?that?both?of?these?two?ways?can?conpound?,?the?phosphor?with?.?In?general,?the?samples?conpounded?by?the?Solid-phase?method?have?the?highest?flourescence?emission?in?1000?through?analyzing?flourescence?spectrum?while?the?Combustion?method?in?1100.Key words: crystallinit