基于电化学阻抗谱的Zn 及Zn–Al 涂层的自封闭机理研究 - 中国表面工程.PDF

2005 2 (71 ) 27 Zn Zn–Al * 1,2 1 3 2 1 (1. 100072; 2. 100022; 3. 100037) Zn–Al Zn Al Zn–Al EISX– XRD Zn Zn–Al Zn Zn Zn–Al Zn-Al EIS TG174.1 A : 1007–9289(2005)02–0027–04 Study on Self-sealing Mechanism of Zn and Zn-Al Coating Based on Electrochemical Impedance Spectroscopy 1, 2 1 3 2 1 LIU Yan , ZHU Zi-xin , MA Jie , LI Zhuo-xin , XU Bin-shi (1. National Key Laboratory for Remanufacturing, Beijing 100072 China; 2. The college of Materials Science and Engineering, Beijng University of Technology, Beijing 100022 China; 3. Department of Chemistry, Capital Normal University, Beijing 100037 China) AbstractPresently, thermal sprayed Zn-Al alloy coating has become the best way to protect steel structure in oceanic circumstance instead of Zn and Al coating. High velocity arc spraying (HVAS) and cored wires techniques were applied to produce Zn-Al anti-corrosion coating, and EIS (Electrochemical Impedance Spectroscopy) measurement in conjunction with the XRD results of corrosion products and SEM analysis of corrosion surface were used to comparatively investigate the corrosion properties of Zn and Zn-Al coatings, and to study the self-sealing mechanism. The results show that the active solution is the main corrosion mechanism of Zn coating. It exhibits self-sealing function in the corrosion process, but the self-sealing effect is weak because of the loose corrosion products. Zn-Al coating represents better corrosion resistance because of the better self-sealing effect, which begins from the