铜锌锡硫的合成及其光电应用.pdfVIP

元机化学学报 第 32 卷第 6 期 Vo1.32 No.6 2016 年 6 月 CHINESE JOURNAL OF INORGANIC CHEMISTRY 968-974 铜铸锡硫的合成及其光电应用 王聪1 赵卿飞女，2 张华女，1 (华东理工大学化学与分子工程学院，上海市功能性材料化学重点实验室，上海 200237) 「上海师范大学化学系，上海 200234) 摘要:铜铸锡硫(CZTS)半导体常作为对电极材料被应用于量子点敏化太阳能电池(QDSCs)中，然而效率一直低于4%。本文采用 热注入法合成出纳米尺寸的 CZTS 并制成对电极(CZTS店10) ，用其组装的 CdSe QDSCs 和 CdSeTe QDSCs 的效率(PCE)分别达到 了 5.75%和 7.6413毛。电化学阻抗谱、塔菲尔极化等表征证明电池效率的提高与 CZTS 良好的导电性及催化活性联系密切。 关键词: CZTS; 热注入合成;量子点敏化太阳能电池;对电极 中图分类号: 0614.6 文献标识码:A 文章编号: 1001-4861(20 16)06-0968-07 DOI: 1O.11862/CnC.2016.116 Copper Zinc Tin Sulfide: Synthesis and Photovoltaic Application WANG Cong1 ZHAO Qing-Fei叼 ZHANG Hua女，1 CShanghai Key LahoraJory of Functional MaJeria1s Chemistry, Eωt China University of Science and Technology, Shanghai 200237 , China) rChemistry Department , Shanghai Normal University, Shanghai 200234) Abstract: Copper Zinc Tin Sulfide (CZTS) semiconductor has been used as counter electrode in QDSCs. However , the highest power conversion efficiency (PCE) of the corresponding QDSCs was lower than 4%. Herein , copper-deficient CZTS was synthesized through modified hot-injection method. The as-prepared CZTS is made into counter electrode (CZTS/FTO). PCEs up to 5.759毛 and 7.649毛 for CZTS/FTO based CdSe and CdSeTe sensitized QDSCs are obtained , respectively. The excellent photovoltaic performance is associated with the good conductivity and catalytic activity of CZTS. Electrochemical impedance spectroscopy (EIS) and Tafel polarization are used to verify the good electrochemical properties of CZTS/FTO. Keyword