不同原料配比对tic晶须合成的影响研究本科论文.docVIP

四川理工学院毕业论文 不同原料配比对TiC晶须合成的影响研究 学 生：张山 学 号：031020128 专 业：材料班 级：指导老师： 二〇一五 年月摘 要 TiC晶须具有晶体结构缺陷小、硬度高、抗弯强度高、熔点高、热稳定性好等优点，常作为金属基复合材料的增强颗粒。本文利用偏钛酸、葡萄糖为前驱体，氯化镍为催化剂，氯化钠为卤化剂，高温碳热还原制备了TiC晶须。采用SEM、XRD检测手段表征TiC晶须的相组成以及显微形貌，探讨了不同卤化剂、催化剂及其添加量对晶须合成的影响。实验结果表明：利用前驱体+气氛碳热还原技术在1300℃下，能成功的合成TiC晶须，直径200nm间。催化剂NiCl2的添加量过少生成的TiC晶须晶粒粗大、形状不规则，产量低；而过多则会形成大量的颗粒；当添加量为TiO2量的40%，晶须品质最好。与其它卤化剂相比，使用低成本NaCl能获得较好品质的TiC晶须。卤化剂NaCl的添加量过少会使晶须晶粒粗大，长径比变小，表面粗糙；而添加量过多则会影响晶须的生长方向，产生絮状物；当添加量为TiO2的80%，得到了品质较好的晶须。 关键词： TiC晶须；前驱体法；碳热还原； ABSTRACT TiC whisker has many advantages such as small crystal structure defects, high hardness, high bending strength, high melting point and good thermal stability, and it is often used as particle-reinforcement for metal matrix composite. In this paper, the superfine TiC whiskers were synthesized by metatitanic acid and glucose as precursors, NiCl2 and NaCl as catalyst and halogenating agent under high temperature, and were characterized by SEM and XRD. The influences of halogenating agents and catalyst to TiC whiskers were investigated. The results show that the TiC whisker was successfully obtained using the technique of precursor and carbon thermal reduction atmosphere at 1300 oC, and the diameter of whisker is 100-200nm. Without enough NiCl2 as catalyst, TiC whisker will be thick, out-of-shape and the output is low. While too much catalyst will lead to form a large number of particles. When NiCl2 is 40% of the amount of TiO2, the quality of TiC whisker is the best. Compared with the other halogenating agents, NaCl is low cost. with can bring good quality TiC whisker. Without enough NaCl, the whisker will low ratio of length to diameter with rough surface. While too much amount of NaCl will influence the growth direction of whisker, and the floccule will come into being. When NaCl is 80% of the amount of TiO2, the quality of TiC whisker is the best. Key words: TiC whiskers, Precursor method, Carbothermal reduction, Material blending ration 目 录 摘 要 I Abstra