木薯吸附剂的改性及吸附性能分析.pdfVIP

Finally, an adsorption experiment of water form liquid-phase ethanol-water mixtures was designed to study the adsorption ability of the modified and native cassava adsorbents, which can prove that the modified cassava adsorbents had better absorptive properties than the native ones. The time of adsorption as well as the water removed under different ethanol concentrations were investigated. The modified cassava adsorbent was compared with the commercial molecular sieves in terms of adsorption capacity form liquid-phase ethanol-water mixtures. And it was proved that the modified cassava adsorbent had capacities similar to commercial molecular sieves, and even bigger than commercial molecular sieves under some certain water concentration of ethanol-water mixtures. The physical strength of the modified starch adsorbents was proved to meet the need of normal application when the water mass concentration of the ethanol-water solution was less than 20 %. Key words: Fuel ethanol, Dehydration, Biomass adsorbent, Microporous starch, Liquid-phase adsorption 目 录 第一章 文献综述1 1.1 研究背景1 1.2 燃料乙醇的制备3 1.2.1 燃料乙醇工业生产方法3 1.2.2 发酵法制燃料乙醇常见原料3 1.2.3 发酵法制燃料乙醇工艺简介4 1.3 燃料的生产工艺4 1.3.1 特殊精馏工艺5 1.3.2 膜分离制燃料乙醇5 1.3.3 吸附法制燃料乙醇5 1.4 吸附法制燃料乙醇中吸附剂的种类6 1.4.1 分子筛6 1.4.2 生物质吸附剂6 1.5 生物质吸附及生物质吸附剂改性7 1.5.1 生物质吸附法7 1.5.2 生物质吸附剂改性9 1.5.3 生物质吸附剂吸附方式的选择11 1.6 生物质吸附机理13 1.7 本文研究内容14 第二章 实验方法和分析方法16 2.1 实验材料及仪器16 2.1.1 实验原料16 2.1.2 实验仪器16 2.1.3 实验装置图17 2.2 实验测试与表征方法18 2.2.1 水份测定仪的校正与使用方法18 2.2.2 气相色谱的使用方法19 2.2.3 表征方法及操作条件21 2.3 实验步骤与方法21 2.3.1 木薯淀粉水解制备微孔淀粉21 2.3.2 乙醇-水体系不同吸附时间吸附效果的测定22