水溶性有机物对菲的表观溶解度与正辛醇_水分配系数的影响_占新华.pdfVIP

26 1 　　　　　 Vol. 26, No. 1 2006 1 　Acta Scientiae Circum stantiae Jan., 2006 , , 　. 2006. /[J]. , 26(1):105 - 110 Zhan X H, Zhou L X, Huang K. 2006. ffect of dissolved organicmatter (DOM )on the apparentwater solubility and the n-octanol /water partition coefficient of phenanthrene[J]. A cta Scientiae Circumstantiae, 26(1):105 - 110 / * 占新华,周立祥 ,黄　楷 南京农业大学资源与环境学院环境工程系, 南京 210095 :2005-08-24　　　:2005-11-05　　　:2005-11-21 :、(DOM ), (Phe)(PAH s), DOM /. , . -1 DOM , , . DOM 150 mg L ( DOC), Tween-80、DOM、 DOM DOM 20.39、2.082、1.838 1.549 . DOM , . DOM , 4 DOM Tween-80 DOM DOM DOM ., DOM / , logK ow ., DOM PAHs / . :;;;- :0253-2468(2006)01-0105-06　　　:X13　　　:A Effect ofdissolved organicmatter (DOM )on the apparentwater solubility and then - octanol/water partition coefficient ofphenanthrene * ZHAN X inhua, ZHOU Lixiang , HUANG Kai Department of nvironmental ngineering, College of Resources and nvironmental Sciences, N anjingAgriculturalUniversity, Nanjing 210095 Received 24 August 2005;　　　received in revised form 15N ovember 2005;　　　accepted 21 November2005 Abstract:Batch expermi ents with a shake-flask method were carried out to investigate effect of dissolved organicmatter (DOM )derived from green manure, pig manure, and sewage sludge on the apparent aqueous solubility, and then-octanol /water partition coefficient of phenanthrene (Phe). The results showed that the dissolution of Phe in purewater could be described by smi ple firs-t order kinetics. The equilibrium tmi e ofPhe dissolved in water was lagged and Phe apparent solubility increased due to the addition ofDOM .The apparentwater solubility of Phe in the presence of 150 mg L- 1 could