碳纳米管的拉曼光谱及其温度效应RamanSpectraofCarbon.PDF

10　 1 　　　　 Vol. 10 No . 1 19984 CHIN ESE JOURN AL O F LIGHT SCATT ERING Apr. 1998 　　 黄福敏　余国滔　谭平恒　张树霖 (　　 100871) 施祖进　周锡煌　顾镇南 (　　 100871) * 　　 , D D 。, ,,,。 　　　 　O697. 38 Raman Spectraof CarbonNanotubes and Their Temperature Effect 1 2 1 1 Huang Fumin , Yue Kw ok To , Tan Ping eng , Z ang S ulin 1 2 ( Dep artmen t of Phy sics and Col lege of L if e Sciences , Peking University , B eij ing　 100871) S i Zujin, Z ou Xi uang, Gu Z ennan (Dep ar tmen t of Ch emistry , P eking University , B eij ing　 100871) Abstract　We present t e first report of fourt order Raman peaks of car- bon nanotubes at room temperature. An unusual discrepancy betw een t e fre- * quency of t e Stokes and anti-Stokes peaks of t e D and D mode is found. , Furt ermore w e observe a temperature dependence of t e frequency of all t e major peaks in t e Raman spectra of carbon nanotubes and active carbon us-, ing different excitation laser pow ers at t e sample. T e frequency decreases linearly wit increasing temperature for all peaks, but by different amounts. T e origin of t is temperature dependence is not clear but may be due to t e nanoscale features of carbon nanotubes and active carbon. Key Words　carbon nanotubes, abnormal Raman p enomenon, tempera- ture effect