原位聚合聚苯氨包覆碳纳米管的研究.pdfVIP

　原位聚合聚苯氨包覆碳纳米管的研究 3 原位聚合聚苯氨包覆碳纳米管的研究 The Char act eri stic s of t he Car bon N anot ube Coat ed wit h Polyaniline Throu gh Polymer atio n of A niline i n s i t u 曾效舒 ,傅燮莲 ,曹 　东 ,李文唐 ,徐春水 (南昌大学 机械电子工程学院 ,南昌 330029) ZEN G Xiaoshu , FU Xielian , CA O Don g , L I Went ang , XU Chunshui , (Mechanical Elect ronic College , N anchan g U niver sit y ,N anchang 330029 ,China) 摘要 : 进行了用苯氨单体在含有分散碳纳米管的环境中发生聚合 ,使聚苯胺包覆碳纳米管 ,然后把这些碳纳米管添加到 聚丙烯中的实验 。利用透射电子显微镜 ,X 射线衍射仪对碳纳米管的分散效果 ,碳纳米管/ 聚苯胺界面进行了分析 ,检 测 。对加有碳纳米管/ 聚苯胺的聚丙烯进行了抗拉强度测试 ,并对试样弯曲断裂断口进行了扫描电镜分析和 ED S 分析 。 结果表明苯胺可以很好地在碳纳米管上形核聚合 ,形成的聚苯胺能够完全包覆和缠绕在碳纳米管上 ,从而有利于碳纳米 管处于很好的分散状态 。包覆有聚苯胺的碳纳米管添加到聚丙烯中提高了聚苯烯的力学性能 ,与不添加填料的聚苯烯 相比,在相同实验条件下添有包覆聚苯氨的碳纳米管 2 %的聚苯烯常温拉伸强度提高了70 % 。 关键词 : 碳纳米管 ;复合材料 ;聚苯胺 ;界面能 ;分散 ( ) 中图分类号 : TB383 　　文献标识码 : A 　　文章编号 : 100 14381 2006 Abstract : The exp eriment s have been p erfor med t hat t he car bon nanot ube s in di sp er sion were coat ed wit h p olyaniline by polymeration of t he aniline i n s i t u on t he CN Ts and t here mwcnt s were added into polyp rop ylene . The mwcnt s coat ed wit h polyaniline were ob served u sing T EM , and Xray diff raction . The polyp rop ylene samp le s wit h p olyanlinecoat ed mwcnt s were t e st ed t en sile st ren gt h an d t he mor p hour s an d t he co mpo sition of t he samp le f ract ure sectio n were al so ob served and analy sized u sing SEM and ED S. The se re sult s show t hat polyaniline can cover on CN T at all , and adhere to surf ace of M WCN Ts very well . The t en si