利用中低温余热有机朗肯循环工质选择.pdf

利用中低温余热的有机朗肯循环的工质选择 1 1 2 1 冯永强 ，李炳熙 ，杨金福 ，韩怀志 （1 哈尔滨工业大学，能源科学与工程学院，哈尔滨 150001） （2 中国科学院，中科院工程热物理研究所，北京 100190） 摘 要 ：基于中低温余热（150-500℃）作为热源的有机朗肯循环系统，选取苯，R11 ，R113 ， R123 ，R245ca 等有机工质，依据理想朗肯循环热力学模型，计算了各种有机工质循环效率， 随后与水和氨工质进行分析比较 ，最后对制冷剂替代工质循环效率进行了分析计算。结果表 明：在中低温余热热源有机朗肯循环中，循环效率最高的为水，其次为苯，然后是R11 ，R113 和R123 ，氨循环效率最低；R11 适合于热源温度较高压力较大的系统，R113 适合于热源温 度不高压力不大的系统；替代工质中，出于安全性和环保性的考虑，R245ca 和R245fa 是比 较适合的工质。 关键词：有机朗肯循环 中低温余热热源 工质选择 Working Fluid Selection for Low and Medium Temperature Waste Heat Organic Rankine Cycles 1 1 2 1 FENG Yong-qiang ；LI Bing-xi ； YANG Jin-fu ； HAN Huai-zhi （1 School of Energy Science and Engineering, Harbin Institute of Technology, Harbin 150001, China ） （2 Institute of Engineering Thermo-physics Chinese Academy of Sciences, Chinese Academy of Sciences ， Beijing 100190, China ） Abstract: Based on the low and medium temperature （150-500℃）waste heat organic Rankine cycle, some organic fluids such as benzene, R11, R113, of R123, R245ca were selected. The system efficiency of different working fluids was calculated using the ideal Rankine cycle thermodynamic model and compared with water and ammonia . Finally, alternative refrigerant was analyzed. The outcomes indicate that in the low and medium temperature waste heat organic Rankine cycle, the system efficiency of water is greatest, followed by benzene, R11, R113, R123, and the lowest is ammonia; R1 1 is suitable for recovery waste heat at higher pressure and higher heat source temperature; R113 is suitable for recovery waste heat at lower pressure and lower heat source temperature; consideration of safety and environmental 第一作者：冯永强，1985 年12 月生，男，博士研究生，主要从事可再生能源余