红壤水稻土包气带三氮迁移转化规律研究.pdfVIP

摘 要 以江西千烟洲农业生态系统内水稻田为研究对象，通过定期采集包气带土壤溶液和室 内化学分析的方式，以氨氮、亚硝酸盐氮、硝酸盐氮为研究内容，对包气带土壤溶液中三 氮迁移转化规律进行研究，为氮素污染地下水的预测和定量评价提供科学依据。试验结果 表明：早稻时段氨氮含量较低，无明显波动，而亚硝酸盐氮、硝酸盐氮累积明显；晚稻时 段硝化反应受到抑制，氨氮出现明显累积，亚硝酸盐氮、硝酸盐氮含量变幅较小，无明显 累积，随着时间的增加，氨氮逐渐趋于动态平衡；三氮在不同深度包气带土壤溶液中有明 显的迁移特征：40～120cm 深度土壤溶液中氨氮含量最高；20～120cm 深度土壤溶液中亚 硝酸盐氮浓度先升高后降低；硝酸盐氮含量随着深度增加反硝化消耗逐渐减小。通过对不 同深度土壤溶液中铁锰含量与三氮含量的相关分析确定了包气带中影响三氮迁移转化的 主要铁锰浓度场位；120cm 深度铁锰含量呈显著性正相关，铁锰的伴随关系良好，三氮变 化受铁锰浓度场的控制显著；其他层段三氮与铁锰含量的相关性不显著；氨氮、亚硝酸盐 氮与铁锰含量呈显著性正相关，硝酸盐氮与铁锰含量呈极显著性负相关。 关键词：三氮；包气带；迁移转化；铁锰 - I - Abstract This thesis is mainly about the transportation and transition regulation of nitrogen in unsaturated zone. Ammonia-nitrogen, nitrite-nitrogen and nitrate- nitrogen are used as the research object, combining with collection of soil solution regularly and monitoring. The site of this research locates in the rice fields of the agricultural ecosystem located in Qianyanzhou, Jiangxi. The scientific basis will be provided for prediction and quantitative assessment of the nitrogen pollution in groundwater. The test results show that the content of ammonia-nitrogen is low during the period of early rice, while nitrite-nitrogen and nitrate- nitrogen are high obviously. The nitration reaction is inhibited during the period of late rice, then ammonia-nitrogen are high obviously. As time increases, ammonia-nitrogen tends gradually dynamic equilibrium. Three-nitrogen at different depths in water has obvious characteristics of migration. The content of ammonia-nitrogen is highest in the soil solution during 40~120cm, the content of ammonia- nitrogen rises at first, then decreases during 20~120cm, and the content of nitrate-nitrogen decreases gradually with depth’s