聚乙二醇的添加对於硷液中锌的腐蚀行为影响研究-中华民国防蚀工程.PDFVIP

聚乙二醇的添加對於鹼液中鋅的腐蝕行為影響研究 防蝕工程　第二十三卷第一期　第13 ～ 22 頁　2009 年3 月 Journal of Chinese Corrosion Engineering, Vol. 23, No. 1, pp. 13 ~ 22 (2009) 王志華* 、洪耀宗 Effects of Polyethylene Glycol on the Corrosion of Zinc in Alkaline Media J. H. Wang*, Y. T. Horng Received 20 July 2007; received in revised form 7 April 2008; accepted 6 May 2008 本文針對鋅在含聚乙二醇(PEG)之 8 M 氫氧化鉀溶液中的腐蝕行為進行研究。研究結 果發現，平均分子量為400 與 600 的聚乙二醇(PEG400 與 PEG600)皆可在極短時間內大幅 降低鋅的腐蝕電流，而且PEG600 的防蝕效果優於PEG400 。PEG400 或PEG600 在 8 莫耳 氫氧化鉀溶液中的適當添加重量百分比約為0.2% 。在初期的10 天內，PEG600 對於鋅陽極 的保護效率可高達 90%以上。當浸漬時間由 10 天延長為 30 天，PEG600 的保護效率會遽 減約 16% 。PEG 保護效率的變化與電化學交流阻抗測試以及表面顯微觀察的結果極為一致。 關鍵詞：聚乙二醇；保護效率；交流阻抗。 ABSTRACT The electrochemical characteristics of zinc in 8 M KOH electrolytes containing polyethylene glycol (PEG) were investigated. It was found that PEG400 (PEG with an average molecular weight of 400 g/mol) as well as PEG600 could dramatically decrease the corrosion current of zinc in extremely short time. In addition, the protection efficiency of PEG600 was superior to that of PEG400. The optimum concentration of either PEG400 or PEG600 addition in the 8M KOH electrolyte is around 0.2%. During the first ten days of storage, the PEG600 provided zinc with a rather high protection efficiency of 90% from corrosion. However, an abrupt drop of protection efficiency, about 16%, was observed when the storage time was extended to 30 days. This decline of protection effic