PU涂料基础培训.pdf

Basic Chemistry of Polyurethane Coatings 聚氨酯涂料基础化学 By Fengwan Wang 王丰万 Feb. 2007 Feb. 08 2007 CAS-PS-APAC Introduction 简介 During the late 1930’s, Otto Bayer and his co-workers pioneered the chemistry of polyisocyanates, a technology which led to the advent of polyurethanes for a variety of applications. Since 1955 Bayer Corporation has introduced a variety of monomeric and polymeric isocyanates, polyesters, polyethers, and acrylics for use in the formulation of polyurethane coatings. 二十世纪三十年代后期，奥托·拜耳及其同事奠定了聚氨酯化学的 基础，并开发出适合不同用途需要的聚氨酯技术。 自1955年以来，拜耳公司已把各种单体和聚合的异氰酸酯、聚酯、 聚醚及丙烯酸酯应用于聚氨酯涂料的生产配方中。 CAS-PS APAC Wang Fengwan Feb. 08 Page 2 Typical Formulation of Coatings 涂料的典型配方 Solvents Additives Pigments Extenders Resins CAS-PS APAC Wang Fengwan Feb. 08 Page 3 Typical Paint Solvents 常用溶剂 • Aromatic hydrocarbons-Toluene, Xylene 芳香烃类，如甲苯、二甲苯 • Aliphatic hydrocarbons 脂肪烃类 • Ester acetates-EA,BA 乙酸酯类，如乙酸乙酯、乙酸丁酯 • Alcohols-Butanol 醇类,丁醇 • Ketones- MEK, Acetone 酮类，如丁酮、丙酮 • Glycol ethers and ether acetates-MPA，EEP 醇醚及醚酯类，如丙二醇甲醚醋酸酯，3－乙氧基丙酸乙酯 • Others- 2-nitropropane 其它，如2-硝基丙烷 CAS-PS APAC Wang Fengwan Feb. 08 Page 4 Additives 助剂 Additives that is one of coating ingredients modify the behavior of the bulk liquid or coating film. 助剂，是涂料的一个组成部分，能对涂料或涂膜的某 一特定方面的性能起改进作用。 Additive types are chosen according to the functional requirements of coating and paint film. 根据不同涂料或涂膜的要求可选用不同助剂。 CAS-PS APAC Wang Fengwan Feb. 08 Page 5 Types of Additives 助剂类型 • Ad