一种新型单基质白光LED荧光粉Ca8MgBiPO47_Dy3+的制备与性能研究.docVIP

  A novel white emission in Ca8MgBi(PO4)7:Dy3+ single-phase full-color phosphor# 1,2 2 1 1 1** 5 10 (1. State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, China; 2. Hebei Normal University of Science and Technology, Qinhuangdao, 066600, China) Abstract: Novel single-phased white-light-emitting Ca8MgBi(PO4)7:Dy3+ phosphors for light-emitting diode (LED) applications were synthesized by conventional solid-state reactions. The phases and luminescent properties of the obtained Ca8MgBi(PO4)7:xDy3+ phosphors were well characterized. The results show that the excited bands of Ca8MgBi(PO4)7:xDy3+ phosphor centered at wavelengths of 324 nm (6H15/2 4 M17/2), 350 nm (6H15/2 4M15/2, 6P7/2), 366 nm (6H15/2 4 I11/2), 387 nm (6H15/2 4I13/2, 4F7/2), 427 nm (6H15/2 4 3+ consisted of double emission bands, which can be assigned to the transition emissions of 15 4 6 single-component white-light-emitting phosphor for UV-light-emitting diodes. Key words: Single-phase phosphors; Ca8MgBi(PO4)7:Dy3+; White LED 0 Introduction In recent years, Light-emitting diodes (LEDs) have received wide attention because of their 20 25 30 high brightness, material hardness, long lifetime, and environmental friendliness [1]. As we all known, the combination of UV LED chips and the red/green/yellow/blue light emitted from the phosphors exhibit their superior color uniformity with a high color rendering index and excellent quality of light. However, for this combination, the light reabsorption and the matching ratios among different color phosphors severely influnced on the luminous efficiency. Meanwhile, single-phase full-colour white phosphors that can be effectively excited in the NUV range can solve this problem. Trivalent dysprosium (Dy3+) ion has two intense emission bands in the blue (470–500 nm) and yellow region (560–600 nm). By adjusting the yellow to blue (Y/B) intensity