秦蒙的毕业论文.docxVIP

毕业论文题 目：丝网印刷工艺对掺杂氧化铈基极限电流型氧传感 器的性能影响学生姓名：秦蒙学 号：1161142129专 业：无机非金属材料工程班 级：无机一班指导教师：周芬 副教授丝网印刷工艺对掺杂氧化铈基极限电流型氧传感器的性能影响摘 要随着我国经济实力的快速增长，伴随产生的环境、资源、社会伦理道德等问题也日益突出。为了达成可持续发展的愿景。我们课题组所研究的氧传感器恰好响应了国家的号召。当然也具有较好的前景。本篇论文使用LaNi0.6Fe0.4O3（LNF）和La1-xSrxCo1-yFeyO3（LSCF）固体电子-离子混合导体材料作为氧传感器的致密扩散障碍层材料，通过丝网印刷工艺刷制不同层数的阴极在SDC基片上以制备了不同厚度的致密扩散障碍层极限电流型氧传感器。制备固体电解质材料Ce0.8Sm0.2O1.9（SDC），文中采用溶胶凝胶法来制备,对制备出的粉体应用X射线衍射分析仪（XRD）对该粉体进行了物相分析，同时通过阅读文献制定和优化了烧结制度来制备SDC陶瓷片。采用溶胶凝胶法制备了致密扩散障碍层粉体LNF和LSCF，应用X射线衍射分析仪（XRD）对粉体物相进行了表征。并且在查阅相关文献的条件下，制备出LaNi0.6Fe0.4O3（LNF）和La1-xSrxCo1-yFeyO3（LSCF）为阴极障碍层的致密扩散粉体。将烧结好的SDC陶瓷片，用砂纸打磨粗糙后，再用松油醇研磨的LNF或LSCF浆料涂刷在SDC陶瓷片上，再进行烧结即可。尔后利用扫描电子显微（SEM）、电化学工作站对其进行断面结构分析和电化学性能分析关键词：氧传感器；极限电流；SDC；致密扩散障碍层；LNF;LSCFSilk screen printing process for doped cerium oxide base of limiting current type oxygen sensor device performance impactAbstractWith the rapid growth of China’s economy , the constant improvement of the comprehensive national power and our country in the world’s superpower status. At present, the research studied the oxygen sensor just responded to the call of the state. the dense oxygen diffusion barrier layer of limiting current type oxygen sensor has higher sensitivity and wider measurement range, the response speed is faster and better stability than before. In the paper, the solid electron-ion mix conductor material LaNi0.6Fe0.4O3（LNF）and La1-xSrxCo1-yFeyO3（LSCF）is used as materials of dense diffusion barrier of sensors and the dense diffusion barrier limiting current oxygen sensor was developed successfully through the technology of Pt liquid agglutination, and oxygen sensitivity is tested by limiting current oxygen sensor testing equipment.The solid electrolyte material Ce0.8Sm0.2O1.9(SDC) is prepared by sol-gel method. X-ray powder diffraction(XRD), scanning electron microscope(SEM) were applied to characterize the compositions and morphologies of the powder. The sintering shrinkage and sintered density are studied. The SDC solid electrolyte ceramic mater