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中国联塑 聚氯乙烯(PVC)知识(国外英文资料)
中国联塑 聚氯乙烯(PVC)知识(国外英文资料)
Polyvinyl chloride is the most characteristic flame retardant, so it is widely used in fire protection applications. But polyvinyl chloride releases hydrogen chloride and other toxic gases, such as dioxins, in the process of burning.
The combustion of PVC is divided into two steps. The hydrogen chloride gas and the diene containing double bonds are first decomposed at 240 DEG C -340 DEG C, and then carbon combustion occurs at 400-470 DEG C.
Physical and chemical properties
Stable; not susceptible to acid or base corrosion; relatively resistant to heat
PVC is flame retardant (flame retardant is 40 or above), chemical resistance (resistance to high concentrated hydrochloric acid, sulfuric acid concentration of 90%, concentration of nitric acid and sodium hydroxide concentration of 20% 60%), has the advantages of good mechanical strength and electrical insulation. But its heat resistance is poor, softening point is 80 degrees, at 130 degrees, it begins to decompose, change color, and precipitate HCI.
The main industry of PVC resin is amorphous structure, but also contains some crystal region (about 5%), so the PVC has no obvious melting point, about 80 degrees Celsius to soften, heat distortion temperature (1.82MPa load) at 70-71 DEG C and 150 C under pressure to flow, and slowly begins to release hydrogen chloride, resulting in PVC color (by Huang Bianhong, brown and even black). The average relative molecular weight of the industrial PVC is in the range of 4.8-4.8 million, and the corresponding average molecular weight is 2-1.95 million. While the vast majority of industrial resin weight average molecular weight of 10-20 million, the number average relative molecular mass in 4.55-6.4 million. Hard PVC (without plasticizer) has good mechanical strength, weather resistance and fire resistance, can be used as structural material, used in chemical manufacturing, sheet metal and plastic pipes product. Rigid PVC can be reinforced with material
Appl
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