淮南潘集煤矿复垦区土壤重金属含量及形态分布特征.docVIP

  淮南潘集煤矿复垦区土壤重金属含量及形 态分布特征# 江培龙1，方凤满1,2，焦华富1，张杰琼1，邓正伟1** 5 10 15 20 25 30 35 40 （1. 安徽师范大学国土资源与旅游学院，安徽 芜湖 241003； 2. 安徽自然灾害过程与防控研究省级实验室，安徽 芜湖 241003） 摘要：以淮南矿区挖深垫浅式复垦区为研究对象，对该复垦区土壤 Zn、Pb、Ni、Mn、Cu、 Cr 和 As7 种重金属含量进行分析和评价。结果表明，该复垦区土壤中 Ni、Mn、Cu、As 的 平均含量均高于土壤背景值，但均未超过土壤二级标准。蔬菜大棚土壤中 7 种重金属的含量 均高于林地土壤的含量，除 As 外，林地土壤中其余 6 种重金属的变异系数均大于蔬菜大棚 土壤的变异系数。形态分析表明，该复垦区 Zn、Ni、Cu、Cr 和 As 以残渣态为主，Mn 和 Pb 以铁锰氧化物结合态为主。除未复垦对照样点的综合污染指数最小为 0.97，处于警戒线 位置外，其余 18 个复垦土壤的综合污染指数的分布范围为 1.12-1.81，均表现为轻度污染。 林地和大棚地的综合污染指数平均值分别为 1.41、1.48。 关键词：淮南矿区；土地复垦；土地用途；重金属；污染评价 中图分类号：X53 Speciation and Concentration of heavy metals in Reclaimed Soils at Huainan city coal Mine JIANG Peilong1, FANG Fengman1,2, JIAO Huafu1, ZHANG Jieqiong1, DENG Zhengwei1 (1. College of Territorial Resources and Tourism.Anhui Normal University, AnHui WuHu 241003; 2. Anhui Key Laboratory of Natural Disaster Process and Prevention, AnHui WuHu 241003) Abstract: Samples were collected around Huainan reclamation of coal mine. applied the single factor pollution index method and the integrated pollution index method to assess the pollutions status of heavy metals(Zn、Pb、Ni、Mn、Cu、Cr、As)．The results showed that the concentration of such heavy metals as Ni、Mn、Cu、As in reclaimed soil exceeded background value of Huainan soil. The concentrations of all 7 heavy metals in reclaimed soil were not beyond National soil Environmental Quality Standard of GradeⅡ. The concentrations of all heavy metals in vegetable greenhouse soil were higher than forest land.The variation coefficient of heavy metals(Zn、Pb、 Ni、Mn、Cu、Cr) in vegetable greenhouse soil were lower than forest land. Sequential extrations suggested that in the reclaimed soils ,Zn,Ni,Cu, Cr,As were mainly composed with residual fraction.While Mn,Pb were donimated by Fe-Mn oxide form.The integrated pollution index of reference soil was recognized warning limit (0.97), The integrated pollution index of other 18 soils were between1.12 and 1.81,were slight pollution. The integrated pollution in