2,4D的降解实验.pptVIP

Enhanced catalytic hydrodechlorination of 2,4-dichlorophenoxyacetic acid by nanoscale zero valent iron with electrochemical technique using a palladium/nickel foam electrode 马晓云 1. Enhanced catalytic hydrodechlorination of 2,4-dichlorophenoxyacetic acid 2.Synergistic technology combined nZVI with electrochemistry 3.Palladium loading and current density had a greater impact on efficiencies 4.nZVI promoted the generation of electron and enhanced the dechlorination highlights objectives To explore whether there were synergistic effect between electrochemical technology and nZVI, and how was the effect; To evaluate factors affecting 2,4-D hydrodechlorination in the synergistic system, including palladium loading, nZVI dosage and current density; To discuss the reaction mechanism of this synergistic system for 2,4-D hydrodechlorination. Results and discussion Fig. 1. The XRD patterns of (a) catalytic electrodes and (b) nZVI. Results and discussion Fig. 3. The TEM micrograph of nZVI. Results and discussion Fig. 2. The SEM micrographs of (a) fresh Ni foam electrode and (b) Pd/Ni foam electrode. Results and discussion Fig. 4. The EDX spectra of Pd/Ni foam electrodes (a) before and (b) after reaction. Results and discussion Synergistic effect between electrochemistry and nZVI on 2,4-D hydrodechlorination Results and discussion Effects of palladium loading Results and discussion Effects of palladium loading Results and discussion Effects of nZVI dosage Results and discussion Effects of nZVI dosage Results and discussion Effects of current density Results and discussion Effects of current density