大部分玻璃Fe-Cr-Mo-C-B合金.pdfVIP

Corrosion Science 44 (2002) 1847–1856 /locate/corsci Bulk glassy Fe–Cr–Mo–C–B alloys with high corrosion resistance S.J. Pang *, T. Zhang, K. Asami, A. Inoue Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan Received 20 July 2001; accepted 13 December 2001 Abstract The preparation of bulk glassy alloys with high glass-forming ability and high corrosion resistance in Fe-based syste mwas succeeded by means of copper-mold casting. The temper- ature interval of supercooled liquid region (DTx ) is as large as 53–62 K and the reduced glass transition temperature (Tg =T ) is as high as 0.62–0.63 for the cast Fe50x Cr16Mo16C18Bx (x ¼ 4, 6, 8 at.%) glassy alloys. The corrosion rates of the Fe50x Cr16Mo16C18Bx glassy alloys with a diameter of 1.2 were in the range of 103– 102 year1 in 1, 6 and 12 N HCl solutions at 298 K. The bulk glassy alloys are spontaneously passivated in 1 and 6 N HCl solutions with wide passive region and low passive current density. They do not suffer pitting corro- sion even when polarized anodicly in 12 N HCl solution up to 1.0 V (Ag/AgCl). The high corrosion resistance is due to the formation of chromium-rich passive films during i ersion in HCl solutions. In addition, the increase of boron content in alloys improves the corrosion resistance of the bulk glassy alloys within the composition range examined. 2002 Elsevier Science Ltd. All rights reserved. Keywords: Bulk metallic glass; Iron-based alloy; Copper-mold casting; Glass-forming ability; Spontaneous passivation 1. Introduction For the last three decades, a variety