GC-EI-MS 内标法分析鱼肉中邻苯二甲酸酯GC-EI-MS Internal.PDF

2007 65 Vol. 65, 2007 24 , ACTA CHIMICA SINICA No. 24, · · GC-EI-MS a,b *,b a ( 410128) (b 361005) Florisil , (GC-EI-MS)8 (PAEs): (DEP)(DPrP) (DBP) (BBP)(DPeP)(DCHP)(DHP)(2- )(DEHP). , ; , ; ; 5 . 50.0800 µg•L1, (R)0.99986, (Relative standard deviation, RSD)12.7%, (Limit of detection, LOD)3.66 µg•L1, 74.0%113%. LOD PAEs . ; ; GC-EI-MS Internal Standard Analysis of Phthalic Acid Esters in Fish TAN, Juna,b LIN, Zhu-Guang*,b a ( Department of Medicinal Resource Engineering, College of Horticulture and Gardening, Hunan Agricultural University, Changsha 410128) (b Key Laboratory of Analytical Sciences of Ministry of Education, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University , Xiamen 361005 ) Abstract The fish samples were cleaned up by Florisil, then analyzed by GC-EI-MS to determine eight phthalic acid esters, diethyl phthalate (DEP), dipropyl phthalate (DPrP), dibutyl phthalate (DBP), butyl benzyl phthalate (BBP), dipentyl phthalate (DPeP), dicyclohexyl phthalate (DCHP), dihexyl phthalate (DHP) and diethyl hexyl phthalate (DEHP). The external standard and internal standard method were compared, and the pretreatment method was optimized. Especially, the problem of analytical blank control 1 in this exp