finemet合金纳米晶化过程中元素核外电子间相互作用 - 同济大学学报.doc

Finemet合金核外电子相互作用的多普勒展宽谱研究 王宇鑫1,2 严彪1,2(( 赵冠楠1,2 邓文3 (1. 同济大学 材料科学与工程学院,上海200092; 2. 上海市金属功能材料开发应用重点实验室, 上海200092; 3. 广西大学, 南宁 530004) 摘要: 采用双高纯锗探头符合的正电子湮没辐射多普勒展宽谱50℃、380℃和400℃下退火(10min)的Finemet非晶薄带的商谱，对Finemet合金热处理过程中元素核外电子间的相互作用进行了研究。结果表明，Finemet合金淬火态商谱的谱峰比纯金属元素Fe，Cu，Nb的谱峰要低，Fe和Nb之间存在着3d-4d轨道键合作用。随着退火温度的升高，Fe原子的3d电子与Nb原子的4d电子之间的轨道键合作用增强，商谱谱峰降低，Cu原子易在表面富集，而Nb原子则在非晶薄带中富Fe区域里重新分布。 关键词: Finemet合金 核外电子 多普勒展宽谱 中图分类号: O795 O614 　文献标识码: A The extranuclear electron interaction of Finemet alloy studied by using Doppler broadening spectrum of positron annihilation WANG Yuxin 1,2, YAN Biao 1,2, ZHAO Guannan 1,2, DENG Wen 3 （1. School of Materials Science and Engineering, Tongji University, Shanghai 200092, China; 2. Shanghai Key Lab. of DA for Metal-Functional Materials, Shanghai 200092, China; 3, Physics Department, Guangxi University, Nanning 530004, China） Abstract: The ratio curves of Finemet alloy elements and Finemet amorphous ribbons (annealed at 350℃, 380℃ and 400℃ for 10min respectively) have been measured by using Doppler broadening spectrum of positron annihilation which used two HP-Ge detector coincidence technique to investigate the extranuclear electron interaction during annealing process. Results present that the peaks of asquenched Finemet ribbons is relatively low after a comparison with the ratio curves of pure elements Nb, Fe and Cu. There exists a bonding between 3d orbit electrons in Fe atoms and 4d orbit electrons in Nb atoms. The bonding become more strengthened with the increment of annealing temperature, which caused the peaks of ratio curves decreased. Meanwhile, the Cu atoms tend to enriched in the surface and the Nb atoms would redistribute to the amorphous layer of ribbon which is enriched in Fe atoms. Key words: Finemet alloy; extranulear electron; Doppler broadening spectrum 引言 日本日立金属公司的Yoshizawa等人于1988年发明了Finemet 型合金，该合金在适当温度下退火可得到小于10nm的晶化相和部分非晶的残余组织，具有很好的软磁特性，是目前最受关注的一种纳米软磁材料[1,2]。Finemet合金特殊的组织结构决定了它优异的磁学性能