水性紫外光固化涂料中的光脱羧反应论文.pdfVIP

水性紫外光固化涂料中的光脱羧反应 杨建文怫，吴博1，2，曾兆华·，刘晓暄3，陈用烈1 Water-borne inUV-curable Photodecarboxylation Coating Jianwen Chenl Yangl，BoWul，2，ZhaohuaZengl，XiaoxuanLiu3，Yonglie (1．School Yat—Sen of ofChemistryChemicalEngineering，SunUniversity，Guangzhou510275，China；2．DepartmentofChemistry，College Science，Shantou ofMaterialand University University，Shantou515063，China；3．CollegeEnergy，Guangdong 510006。China) 摘要：制备了一种羧甲基硫醚，3．羧甲基硫代丙烯酸甲酯(MCP)，并研究了它在夺氢性光引发剂存在下 的光脱羧反应。通过1HNMR和GC—MS分析了光反应产物，发现单甲基硫醚CH，S—R和亚乙基二硫醚 R．SCH。CH，S．R为两种重要的光脱羧产物，探讨了羧甲基硫醚底物的光脱羧机理。进一步制备了一种 含羧甲基的二元醇，三羟甲基单羧甲基硫醚丙酯(TMCPE)，将其引入聚氨酯丙烯酸树脂，并用于 水性光固化涂料中，在光固化过程中通过ITX同时引发光固化和光脱羧反应，切除了固化后涂层中的 羧基，提高了涂层的耐水性。 AbstractTheattractiveUV．curablewater—borne kinkof be coating，a environment．friendlycoating，could inwaterresistanceafterUVcuredwiththe simultaneouslyimproved photodecarboxylationtechnique． In inter-molecular mechanismbetween presentresearch，the phOtOdecarboxyIatiOn alpha-carboxyl thioetherand II wasrevealedwith typephotoinitiator GC—MS．Monomethyl ether(R—S—CH2CH2．S．R)werefoundtobethe thioethylene primaryphotodecarboxylationproducts． An with thioetherwas andformulatedintoUV-cur- acrylated oligomeralpha．carboxyl synthesized ablewater．borne whichITXwas as and coating，in employedphotoinitiator accelerator．WiththeUV ofthewater-borne