丁酮-DMF体系与甲苯-DMF体系的常减压气液平衡数据的测定.pdfVIP

Chinese J. Chem. Eng. , 14(6) 825-828 (2ω6) RESEARCH NOTES The Isobaric Vapor幽Liquid Equilibrium of Butanone-DMF and Toluene-DMF at Reduced Pressures* L肌J Chang(刘畅)， WANG Lihua(王丽华)， HE Chaohong(何潮洪)树 and YE Xiangqun(叶向群) Department of Chemical Engineering,Zhejiang University,Hangzhou 310027 ,China Abstract The isobaric vapor-liquid equilibrium data of butanone(l)嗣N， N-dimethylformamide (DM的(2) at l00.92kPa, 93.32kPa, and 79.99kPa and of toluene(1 )-D民1F(2) at l00.92kPa were measured using a m州ified Rose…Williams still. The above data met the thermodynamic consistency test and were ωrrelated with the Wìlson, NRTL , and UNIQUAC equations.ηlese data can be used in the analysis and d创ign of 伽e process that involves separating DMF from butanone and toluene in the leather synthesis industry. Keywords isobaric vapor-liquid equilibrium, N, N-dimethylformamide , DMF , butanone , toluene , Wilson equa- tion , NRTL equation, UNIQUAC equation 1 gas chromatography (GC) and the purities ofbutanone, ís an ímportant toluene , and DMF were found to be 99.9%, 99.5% , and is an intermediate in the and 99.9% , respectively. and is also widely used in the pe翩 synthesis, acrylic spinning, polyester 2.2 Apparatus and dyestuff industries. In a typical The experimental apparatus used in 出is study factory , traditionally, DMF, buta- was a modified Rose-Wi1liams sti1l, which was fa- are used as solvents and are finally vored in previous works[2--41. The det~_l s of the appa-