低压阳极铝箔表面状态对铝箔点蚀行为的影响-材料工程.PDF

22 / 2005 2 Influence of Surface State on the Pitting Corrosion Behaviors of Low Voltage Aluminum Anode Foil , , , ( , 1000 3) JIANG Heng, MAO Wei-min, YANG Ping, FENG Hui-ping ( Department of Materials, University of Science and Technology Beijing Beijing, 1000 3, China) : 300 500 1h , , , 300 1 h , 500 1h , , , : ; ; ; : T G 166. 3: A : 1001-43 1 ( 2005) 02-0022-04 Abstract : T he depth profile of microelements in cold rolled aluminum anode foil for low voltage elec- trolytic capacitor and its etching morphology after annealing at 300 and 500 for 1h w ere investi- gated based on secondary ion mass spectrometry analysis and microstructure observation under scan- ning electron microscope. The specific capacity of the etching foils was also measured. It show ed that microelements may segregate to certain extent on the surface layer and be further enriched at foil de- fects such as dislocations, roll marks et al. The annealing treatment at 300 for 1h could prompt the enrichment of microelements at dislocations, but could not enrich the microelements along the roll marks. The annealing treatment at 500 for 1h could not only enrich the microelements along the roll marks, but also reduce the equilibrium segregation concentration of the microelements at the foil defects w hich distributed more uniformly on the surface Etching pits w ere initiated preferably. at the surface defects w ith higher microelements concentration during the etching process The uni-. form distribution of micro