农作物秸秆COD负荷测定及我国弃置秸秆可能形成的面源COD总量极大值估算.pdfVIP

农业环境科学学报 2ω7.26(5):1977-1981 Joumal o! A萨Q~Environment Science 农作物秸科COD 负荷测定及我国弃置秸料 可能形成的面源 COD 总量极大值估算 廖小红，李汉平 (北京工商大学化学与环境工程学院，北京 l 00J37) 摘 要:为估算幸运国弃宣秸轩可能形成的面源 CO口总量极大值，首先对用于测定废水中非晶 ωD 的传统:i格酸仰回流法进行了改 进，即农作物秸轩样品先在75%浓硫酸条件下进行预济解、然后再接传统酸性葳锵醺惆回流法条件泼行氯化分解，绕过实验证明 改进后的农作物稍科 COD 测定方法确实可行;然后采用改进后的 75%辙硫酸rì.ì!溶解+传统黛锵酸柳回流法分别测定了童医格、稻 草、玉米籽和商~轩的 COD 负街值。络果褒明.实测得到单位绝于秘秤物质所对应的COD 负街值分别为1.301 kgkg- ~丰吉、 绝于 1.247 kgkg-I L311 kgkg→绝干杰米籽、1.415 kg kg-I 绝于高旨在籽，最后估算得到残阁农作物椅桥随意弃.1:可能形成的 绝干黯京、 1 陶渊COD 总簸极大值约为488 J1 1..- ，相当于 2四4 年我倒工业生产和生活排放的 COD 总蜜的 36.4Q品。~目此，稽姿各有关方ïlim 农作物黯轩随愈弃Il可能形成的面源COD 总量及其所伴随的水环境问题的预防与管理给予足够的重视。 关镰词:农作物精桥;奔置;精轩CO口负荷测定;而IJCOD 总缘估嘛 中图分~寄;xso呈 交徽栋iR码:A 文意编号，1672舶2043(2∞7)05-1971-ll号 Detennini吨COD Load of Crop Straws and Estimating Possible Maximal Total Amount of COD from Dis咱 阳rded Crop Straws in China UAOX出胁Ho鸣， UH皿-Ping (School of Cheuùcal and Environmental En阴阳咽， Oeijing Technolngy and 8llilîne.. Unive..坷. Bcijî吨 10ω37， China) Abs阳眈:TQ efJtÏma趾P俑.ìble l!I3liml COD (Ch棚ical üxygen Demand) 酬咽nt m:.m d.i配时ed crop 耐ð.W în Cruna.属vernl e甲erirne血 were carτ1ed ouL Some modi且catÎo阳were 皿ade with 恤ditional m时hod of COD detem由1ation wi曲时id.i c 阴阳siu皿díchromate circumßu- ence which ís used to deterOline COD of wastewater 翩翩pl咽. Crop straw 阳mpl制 we附 di翩翩lved in advance with the 阳，lution of 75% 阳L phuric .acid, and then were decomposcd with acidic poUl$sium dÎchromate circumfluence. It w，嗣 proved 由at 伽e modífied method i. practical and reliable in d毗nniniug COO I制d o! crop ~阳LW samples. Using the improved meth叫COD 阳do of wh崎t StC8w, rice 5阳.W， com s出w I and 阴阳oorghum .恤w were de恤nIÚned. 币1. 町凹吨~dCOD 1阅d were ll制pectively 1.301 , 1.247 , 1.311an