北京市大气气溶胶PM_2_5_中水溶性有机酸的测定.pdfVIP

25 5 　　　　　　 Vol.25, No.5 2004 9 ENVIRONMENTA L CIENCE ep., 2004 PM 2.5 ＊ , , (, 　100871) : PM2.5、、10 . 110～ 280 μg/L (), 1.7%～ 6.0%, 3 3 3 0.995 ～0.999.、、3 10 721ng/m 、362ng/m 、325 ng/m , .., . ###:PM2.5;;; :X513　:A 　:0250-3301(2004)05-0021-05 Determination of Water SolubleOrganic Acids inPM of Atmosphere in Beijing 2.5 City HUANG Xiao-feng, HU Min, HE Ling-yan (tate Key Joint Laboratory of Environment imulation and Pollution Control, College of Environmental ciences, Peking Universi- ty, Beijing 　100871, China) Abstract:Ten w ater soluble organic acids in PM2.5 of atmosphere in Beijing w ere determined by capillary electrophoresis, including low molecular weight dicarboxylic acids, aldehyde acids, ketoacids and methanesulfonic acid.The quantified detection limits ranged f rom 110 to 280μg/L (extract).The precise of peak area was between 1.7%and 6.0%, and the correlation coefficients of standard 3 curve were 0.995 ～0.999.The average total concentrations of the ten organic acids in summer, fall and winter were 721ng/m , 3 3 362ng/m and 325 ng/m , respectively, which were comparable w ith some foreign big cities.Oxalic acid was the most abundant species.By exploring seasonal variations of the acids, their source characteristics were simply discussed. ey words:PM2.5;w ater soluble organic acids;capillary electrophoresis;source characteristics 　　, (capillery electrophoresis, CE) (PM2.5) 10%～ 50%, , 20 %～80%[ 1～3] , .CE 、 (w ater soluble organic compound,W OC). 、, [14] W OC ,