自组装膜引导合成二氧化钛薄膜_杨宏.pdfVIP

2007 7 　　 　　　　　　　 24 　4 　 　 July 2007 CHEMIC L　INDUSTRY　 ND　ENGINEERING Vol.24 　No.4 　　:1004-9533(2007)04-0287-04 杨　宏, 李　 , 张金利 (, 300072) :采用巯丙基三甲氧基硅烷的分子自组装膜层对基材表面进行修饰, 利用低温下氟 酸铵的 配位交换反应, 制备出与基底结合紧密的二氧化 晶态薄膜。磺酸基修饰的基材能够对TiO2 膜的 沉积产生明显的诱导作用, 当(NH )TiF 与H BO 的摩尔比为0.05 ∶0.10 时, 薄膜晶型主要为金红 4 2 6 3 3 石型;比例增大为0.05 ∶0.15 时, 薄膜晶型主要为锐 矿型。 沉积的TiO 晶态薄膜具有良好的透光 2 性。 :自组装;二氧化 ;薄膜 :TQ134.1　: Synthesis of TiO Thin Films Oriented by Self-Assembly Layers 2 Y NG Hong, LI Wei, ZH NG Jin-li (School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China) Abstract:The surfaceof substratewas modified by self-assembled layers of 3-mercaptopropyl trimethoxysilane, which induced the deposition of uniform and integrate nanocrystalline titanium oxide films through the ligand exchange reaction of (NH )TiF at low temperature.The self-assembled layer of sulfonate groups played an 4 2 6 important role in the deposition of titanium oxideon the substrate.When themolar ratio of (NH )TiF H BO 4 2 6 3 3 is 0.05 ∶0.1, the as-deposited TiO filmswere mainly rutile crystallites.When the ratio of (NH )TiF H BO 2 4 2 6 3 3 increased to 0.05 ∶0.15, the as-depos