超声波辅助化学镀制备Ni_B_MgO催化剂及其催化加氢性能.pdfVIP

27 8 2006 8 Vol. 27 No. 8 Chinese Journal of Catalysis Au ust 2006 : 0253- 9837(2006) 08- 0690- 07 : 690~ 696 N-i B/MgO 1 1 1 1 2 1 葛少辉 , 吴志杰, 张明慧 , 李 伟, 牟诗诚 , 陶克毅 ( 1 南开大学化学学院新催化材料科学研究所, 津 300071; 2 国家纳米技术产业化基地, 津 300457) : , N-i B N-i B/ M O , X , M O N-i B ; , N-i B/ M O . , N-i B . , , , . Ni-B/ M O 80 W , 50 e . : ; ; ; ; ; ; ; ; ; : O643 : A Preparation of Ni-B/MgO Catalyst by Ultrasonic Wave-Assisted Electroless PlatingandIts Catalytic HydrogenationPerfor ance 1 1 1* 1 2 1 GE Shaohui , WU Zhij ie , ZHANG Minghui , LI Wei , M OU Shicheng , TAO Keyi ( 1 Institute of New Catalytic M aterials Science, College of Chemistry, Nankai University, Tianj in 3 71, China; 2 Nanotechnology Industrializ ation Base of China, Tianj in 3 457, China) Abstract: A series of amorphous Ni-B alloy and supported N-i B/ M O catalyst samples w ere prepared by silver- catalyzed electroless platin under different ultrasonic conditions. The effects of ultrasonic wave on the struc- ture, composition, surface texture, and dispersion of N-i B particles on M O w ere characterized by inductively coupled plasma, X-ray diffraction, transmission electron microscope, selected area electron diffraction, and scan- nin electron microscopy. The activity of the as-prepared catalyst was tested by hydro enation of sulfolene to sulfolane. In comparison w ith the catalyst prepared w ithout ultrasonication, the presence of proper ultrasonic w a