胜利褐煤液化沥青烯光谱表征 - 燃料化学学报.pdf

第42卷 第6期 燃摇 料摇 化摇 学摇 学摇 报 Vol.42 No.6 2014年6月 Journal of Fuel Chemistry and Technology Jun. 2014 文章编号:0253鄄2409(2014)06鄄0656鄄06 胜利褐煤液化沥青烯光谱表征 王知彩,陈恩生,潘春秀,任世彪,雷智平,水恒福 (安徽工业大学化学与化工学院安徽省煤洁净转化与利用重点实验室 安徽 马鞍山摇 243002) 摘摇 要:以胜利褐煤为原料,通过不同条件下加氢液化制备了相应的沥青烯,利用元素分析、红外光谱、紫外可见光谱和荧光 光谱等分析技术对所制备的沥青烯进行了结构表征,探讨了氢气初压和液化温度对沥青烯结构的影响。 结果表明,胜利褐煤 液化活性高,沥青烯和前沥青烯等重质中间物收率较低。 胜利褐煤沥青烯中芳香体系主要以2 ~3环缩合芳环及联苯类芳香 结构为主。 提高氢气初始压力,可以促进煤的加氢裂解及AS脱羟基。 高温、高氢压有利于AS 中芳环取代基的加氢裂解。 相 对而言,荧光光谱是沥青烯芳香结构的有效表征手段,其荧光光谱特征结果与元素分析、H/ C原子比间存在明显的相关性。 关键词:煤液化;沥青烯;荧光光谱;结构表征 中图分类号:TQ53;O657.3摇 摇 文献标识码:A Spectral characterization of asphaltene from direct liquefaction of Shengli lignite WANG Zhi鄄cai,CHEN En鄄sheng,PAN Chun鄄xiu,REN Shi鄄biao,LEI Zhi鄄ping,SHUI Heng鄄fu (School of Chemistry and ChemicalEngineering,Anhui University of Technology, AnhuiKey Laboratory of Clean Coal Conversion Utilization,Ma爷anshan摇 243002,China) Abstract:A series of asphaltenes were prepared by the direct liquefaction of Shengli lignite under different conditions in this paper. Their structures and compositions were characterized by elemental analysis, FT鄄IR spectroscopy,UV鄄vis spectroscopy and Fluorescent spectroscopy. The influences of initial pressure of H and 2 liquefaction temperature on the structure of asphaltene were also discussed. The results indicate that Shengli lignite displays high conversion of liquefaction,and low yield of heavy intermediates such as asphaltene and preasphaltene. The aromatic systems mainly consist of 2~3 rings condensed nucleus and multi鄄phenyl compounds. Toincreasetheinitialpressure ofH canpromotethehydro鄄crackingofcoalmatrixandtheremoval