蔗渣在四氢化萘中的液化反应 - 林产化学与工业.pdf

24 3 Vol. 24 No. 3 2004 9 Chemistry and Industry of orest Products Sept. 2004 郭贵全, 王红娟, 谌凡更* ( 中国科学院广州化学研究所 纤维素化学重点实验室, 广东 广州510650) GUO G Q : , ,400 10 min 1 h, 18% 30% ; 500 10 min 1 h, 1 , 400 , , ; 500 , , 400 , , , , , : ; ; ; :TQ351. 2 : A :0253- 2417( 2004) 03- 0052- 05 LIQUE ACTION O BAGASSE IN TET RALIN GUO Gu-i quan, WANG Hong-juan, CHEN an-geng ( K ey Laboratory of Cellulose and L ignocellulosics Chemistry, Guangzhou I nstitute of Chemistry, Chinese A cademy of Sciences, Guangzhou 510650, China) Abstract: The liquefaction of bagasse in tetralin with and without iron-based catalyst is studied in this paper. The residue rate and oil yield are approximately 18% and 30% respectively at 400 w hether the react ion are conducted for 5 min or 1 h.T he residue rate is doubled w hen reaction t ime varies from 5 min to 1 h at 500 while oil yield w as reduced.At 400 oil yield is enhanced and residue rate does not change w hen eOOH and e S are impreg- 2 3 nated into bagasse.However, the catalysts do not enhance oil yield at 500 .The reason w hy iron-based catalyst en- hanced oil yield is that iron-based catalyst promotes the transfer of hydrogen free radicals from tetralin onto the free radicals from thermodecomposition of free radical fragments from condensation, which results in the formation of sta- ble compounds that are not easily decomposed or gasified.It is concluded that bagasse is dissolved mainly by tetralin at low temperature and that the decomposition of bagasse i