酸化-复合絮凝法预处理煤化工废水 - 环境工程学报.docVIP

酸化-复合絮凝法预处理煤化工废水 冯一伟，柴涛* （中北大学化工与环境学院，太原030051） 摘 要 煤化工废水是一种高浓度难降解的化工废水，需要进行预处理以降低后续深度处理的负荷。在煤化工废水过滤和酸化沉降的基础上，分别选取聚合硫酸（PFS）、聚合氯化铝（PAC）和明矾三种絮凝剂对酸化处理后的煤化工废水进行凝沉淀实验并比较其处理效果，从而选出最佳絮凝剂PFS用PFS配合聚丙烯酰胺（PAM）作复合絮凝剂（PAM）（PFS）（PAM）：中图分类号 X703 文献标识码 A 文章编号 reatment of coal chemical wastewater by acidification- composite flocculation process Feng Yiwei Chai Tao (School of Chemical Engineering and Environment, North University of China, Taiyuan 030051, China) Abstract Coal chemical wastewater contains a high concentration of pollutants and is difficult to degrade. Hence, its pretreatment is needed to reduce the load of the subsequent intense processing. Following water filtration and acidic precipitation, three different flocculants were selected: polymeric ferric sulfate (PFS), polymeric aluminum chloride (PAC), and alum(KA1(SO4)2·12H2O). We performed flocculation sedimentation experiments successively on the coal chemical wastewater after acidification treatment, and compared the effects of treatment for selecting the best flocculant, and also cooperatively used the coagulant aid polyacrylamide (PAM) to treat the wastewater. Additionally, we discussed the effect of two other kinds of flocculants along with PAM. The results showed that the wastewater reached its optimum condition of acidification after filtration at pH 3, and composite flocculation by PFS compounded with PAM at an approximate mass ratio of 50:1 and adjusted the pH to 8. Using this method, the COD removal rate from the wastewater reached a maximum of 77. 83%. The removal rates of ammonia, volatile phenols, and chromium also decreased significantly, with removal rates of 83.70%, 69.01%, and 95.71%, respectively. The optimal pretreatment method has the advantages of low cost and simple operation, and is an economic and effective way to pretreat coal chemical wastewater. Key words coal chemical wastewater；acidification；composite flocculation；pretreatment 煤化工废水是一种典型的严重污染水源生态环境而且难以处理的工业废水，它来源于煤炭焦化、煤气