喷胶棉黏合剂用自交联核壳结构乳液的制备及表征 - 高校化学工程学报.pdfVIP

第28 卷第1 期 高 校 化 学 工 程 学 报 No.1 Vol.28 2014 年 2 月 Journal of Chemical Engineering of Chinese Universities Feb. 2014 文章编号：1003-9015(2014)01-0071-07 喷胶棉黏合剂用自交联核壳结构乳液的制备及表征 张 静, 胡耀鸿, 谢德龙, 司徒粤, 黄 洪 (华南理工大学 化学与化工学院, 广东 广州 510640) 摘 要：以 羟甲基丙烯酰胺 为交联单体，采用预乳化多步种子乳液聚合法制备了核壳结构喷胶棉黏合剂乳 N- (NMA) / 液。研究了缓冲剂对乳液的黏度和粒径的影响，比较了热处理对常规乳液及核壳结构乳液的漆膜性能的影响。实验结 果表明当NMA 的含量为3.3%时，漆膜的性能最佳。透射电镜(TEM)及马尔文粒度分析证明形成了核壳结构。傅里叶 红外光谱(FT-IR)、接触角、摆杠硬度的测定表明在热处理后，NMA 发生了自交联反应。 关键词：自交联；黏合剂； 羟甲基丙烯酰胺；核壳结构 N- 中图分类号：TQ316.6 ；O648.23 文献标识码：A DOI ：10.3969/j.issn.1003-9015.2014.01.011 Preparation and Characterization of Self-Crosslinking Latex with Core-Shell Structure for Spewing Adhesive ZHANG Jing, HU Yao-hong, XIE De-long, SITU Yue, HUANG Hong (School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China) Abstract: Through multi-step seed emulsion polymerization with pre-emulsion, where the N-methylol acrylamide (NMA) was used as a cross-linking monomer, the latexes with core-shell structure were prepared for Spewing adhesives. The effects of the buffer agent on the latex viscosity and particle size and distribution in latex were studied. The effects of heat treatment on the film’s properties of conventional latexes and core-shell structure latexes were compared. It was found that when the NMA’s content is 3.3%, the paint film has the best performance. Transmission electron microscopy (TEM) and Malvern particle size analysis indicate that the sy