新型多孔材料MOF-199 脱除噻吩硫化物.PDF

中国环境科学 2010,30(4) ：448~452 China Environmental Science 新型多孔材料 MOF- 199 脱除噻吩硫化物 代 伟 1*,庄海棠 2,麻炳辉 1 韩敏敏 1,郑 宇 1,陈庆渺 1 (1.浙江师范大学化学与生命科学学院,浙江 金华 321004 ；2.浙江师范大学物理化学研究所,浙江 金华 321004) 摘要：采用水热法合成新型多孔材料 MOF-199,利用 XRD 、77K 下 N2 吸附等温线和 SEM 表征其结构.运用固定床吸附穿透曲线考察了模 型燃油类型对 MOF-199 吸附分离噻吩的影响.结果表明,MOF-199 在脂肪和芳香模型油中的饱和吸附容量分别为 1.96wt%和 1.85wt%,超 过相关文献报道.MOF-199在含溶解水和纯混合模型油中噻吩硫的饱和吸附容量分别为 2.15wt%和 1.62wt%,脱硫吸附容量降低了 25%. 运 用活性炭分层填装吸附柱技术可使 MOF-199 饱和吸附容量达到 2.12wt%. 关键词：MOF-199；噻吩；脱除 中图分类号：X701 文献标识码：A 文章编号：1000-6923(2010)04-0448-05 1* 2 1 Thiophene sulfide removal with novel porous material MOF-199. DAI Wei , ZHUANG Hai-tang , MA Bing-hui HAN Min-min1 1 1 , ZHENG Yu , CHEN Qing-miao (1.College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua 321004, China ；2.Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, China). China Environmental Science, 2010,30(4)：448~452 Abstract ：Novel porous material MOF-199 was synthesized by hydrothermal synthesis and characterized by XRD, SEM analyses and N2 adsorption at 77 K. Types of simulated oils on adsorptive separation thiophene sulfur was stuied by fixed adsorption bed breakthrough curves. It was found that the saturation capacity of sulfur element for MOF-199 was 1.96wt% and 1.85wt% in the aliphatic and aromatic simulated oil, respectively, higher than those previously reported results. The saturation capacity of sulfur element for MOF-199 was 2.15wt% and 1.62wt% in mositure aliphatic and aromatic simulated oil mixture. However, when moisture existed, the capac