锅炉培训资料NEW剖析.ppt

GE PROPRIETARY CONFIDENTIAL Steam Purity Controls by steam separating equipment design (demister/cyclones), operating condition (drum level/pressure control) and boiler water chemistry (SiO2, Conductivity, pH) Impurities in steam come from boiler water carryover (mechanical and volatile) Typical mechanical carryover at 16 MPa steam drum pressure is 0.05% of boiler water dissolved solids SiO2 causes volatile carryover - increases with increasing SiO2 in boiler water, increasing steam drum operating pressure and reducing boiler water pH Saturated steam purity control limits Na 10 ppb, SiO2 20 ppb GE PROPRIETARY CONFIDENTIAL Product Feed Rates GE PROPRIETARY CONFIDENTIAL CorTrol OS7785 Feed Rate Typical 1- 3 ppm of boiler feed water Theoretically 75 ppm per ppm dissolved O2 with 1-2 ppm product as excess Feed Point Ideally deaerator drop-leg or storage to allow maximum reaction time Boiler feed water pH Minimum 8.8, reactivity increases with increasing pH GE PROPRIETARY CONFIDENTIAL Steamate NA0880 Feed Rate Typical 2 - 5 ppm of boiler feed water Decreases with increasing % unpolished condensate return Increases with increasing pH control 3x increase in product feed rate at BFW and Steam pH = 8.8 versus pH = 9.2 Therefore, accurate pH measurement is important Feed Point Ideally deaerator drop-leg or storage Provides boiler feed water pH elevation to minimize corrosion in preheaters and improve CorTrol OS7785 reactivity with dissolved O2 GE PROPRIETARY CONFIDENTIAL Steamate NA0880 Volatility (Distribution Ratio) NA0880 is a blend of two neutralizing amines with different distribution ratio This allows optimum distribution of amines throughout the entire condensate system Specific conductivity – BFW/steam/condensate NA0880 contributes to BFW/steam/condensate specific conductivity Increasing NA0880 feed rate increases pH and specific conductivity of BFW/steam/condensate GE PROPRIETARY CONFIDENTIAL OptiSperse HP2650 Feed Rate Propor