2热化学（国外英文资料）.docVIP

2热化学 The second chapter. The basis of chemical thermodynamics Section 2 ~ 1 overview of chemical thermodynamics Chemical thermodynamics is the science of studying the law of energy conversion in chemical reactions and phase transitions. The content is divided into two parts: the energy change in the A. process and the direction and the limit of the B. reaction (or phase change). It is characterized by the calculation of chemical thermodynamics by known basic data, which predicts the energy change of chemical reaction and phase change, as well as the direction and the limit. You should pay attention to the following points when using: 1. The closed system is the research of chemical thermodynamics. 2, the study of chemical thermodynamics is macroscopic matter. 3. Chemical thermodynamics studies only the initial and final states of the system. 4. Chemical thermodynamics has no concept of time. Section 2 ~ 2 basic concepts State and state functions 1. The state of existence of a system determined by the physical quantities of a series of characterizing systems (macroscopic), called the state of the system. 2. The state function: the macroscopic property (physical quantity) that determines the system state is the state function of the system. The macro nature of the system is related to each other. After a few determinations, the other one is OK, and the state of the system is determined accordingly. Be careful： (1) the aggregation state of matter and state is different. (2) the state function is only concerned with the state, and is independent of the origin of the state. The change of the state function is only related to the systems constant state, but has nothing to do with the change path. Two, process and approach 1. Process: when the state of the system changes, from the initial state to the final state, we say that the system has undergone a thermodynamic process. Abbreviation process. The process can be carried out under certain conditions. Such as: constant pr