油页岩化学结构CPD 模型的改进.PDF

第 37 卷 第 2 期 中 国 电 机 工 程 学 报 Vol.37 No.2 Jan.20, 2017 2017 年 1 月 20 日 Proceedings of the CSEE ©2017 Chin.Soc.for Elec.Eng. 621 DOI ：10.13334/j.0258-8013.pcsee.151699 文章编号：0258-8013 (2017) 02-0621-07 中图分类号：PK 16 油页岩化学结构 CPD 模型的改进 王擎，王平，柏静儒，贾春霞，王一帆，杨乾坤 (油页岩综合利用教育部工程研究中心( 东北电力大学) ，吉林省 吉林市 132012) Improvement of the Chemical Percolation for Devolatilization Model Based on Chemical Structure of Oil Shale WANG Qing, WANG Ping, BAI Jingru, JIA Chunxia, WANG Yifan, YANG Qiankun (Engineering Research Centre of Oil Shale Comprehensive Utilization(Northeast Dianli University), Ministry of Education, Jilin 132012, Jilin Province, China) ABSTRACT: Based on the thermogravimetric-Fourier KEY WORDS: oil shale; pyrolysis; the chemical percolation transform infrared spectroscopy(TG-FTIR), the chemical for devolatilization (CPD); kinetic parameter; TG-FTIR percolation for devolatilization (CPD) model of the chemical 摘要 ：基于综合热分析仪和傅里叶红外联用技术(TG- structure of oil shale was improved, and the accurate prediction FTIR)，通过引入轻质气体组分官能团模型，改进油页岩化 of the oil shale lightweight gas composition was achieved with 学结构的化学渗透脱挥发分(CPD)模型，实现其对油页岩热 the introduction of the model of light gas composition 解中轻质气体组分析出过程的精确预测。通过 TG-FTIR 对 functional groups. This article studied the pyrolysis kinetics of