nanoporous materials miniaturized reactors - 成功大学.ppt

2003/11/08 多功能碳材料研究室 奈米孔洞材料 ?微小化的反應器 國立成功大學化學工程系 鄧熙聖(教授)、粘耀仁、戴佑理、鄭焙哲、 蔡忠憲、劉信佑、劉啟徵 Nanoporous Materials ? Miniaturized Reactors National Cheng Kung University Department of Chemical Engineering Application of Porous Carbon in Supercapacitors (Electrochemical Capacitors) a. Gasification Raw Material char Porous Carbon b. Chemical impregnation Raw Material slurry Porous carbon c. Etching Raw Material partially etched Porous carbon Electrochemical Capacitors Have High Power Density and Energy Capacity Principle of Energy Storage Conventional capacitors The larger area the electrodes can provide, the more energy can be stored. Carbon can be made with high surface area and porosity. Conventional Capacitors Double Layer Capacitors (small d of double Layer) + (porous electrode) Very high capacitance e.g. S.A. = 1000 m2/g for porous carbon double-layer capacitance = 10 μF/cm2 100 F/g for capacitors with carbon electrodes; more than 1000 times higher than conventional capacitors. Principle of Operation 超高電容目前的應用 a. 消費性電子產品的電力支援系統(backup source) 電視機記憶保護裝置 汽車音響 鬧鐘、程序控制器 相機及攝影機 全球行動通訊系統(global system for mobile communication, GSM): 每5 ms有0.5 ms的pulse power。EC可增加電池壽命。 不斷電系統 筆記型電腦、 行動電話 電動玩具、電動牙刷、電動刮鬍刀 b. 各種機械、引擎的啟動器, 尤其寒冬下可取代電池。 c. 交通號幟的電力供應 d. 電動汽/機車 以上應用均是利用其瞬間高放電、 快充電、可靠性高及壽命長等特點。 Preparation of Ordered Mesoporous Carbon and Applications Mesoporous silica, like MCM48, SBA15…, etc,has been used to synthesis ordered mesoporous carbon in recent years. Compare with traditional active carbon, mesoporous carbon not only reserves high specific surface (ca. 1500 cm2/g), but also has uniform pore size and regular nanostructure. It can be used as catalytic supports, electrode materials, … etc. Synthesis Mechanism TEM image and SBET Applications Anodic catalyst support for direct methanol