- 1、本文档共29页,可阅读全部内容。
- 2、原创力文档(book118)网站文档一经付费(服务费),不意味着购买了该文档的版权,仅供个人/单位学习、研究之用,不得用于商业用途,未经授权,严禁复制、发行、汇编、翻译或者网络传播等,侵权必究。
- 3、本站所有内容均由合作方或网友上传,本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺!文档内容仅供研究参考,付费前请自行鉴别。如您付费,意味着您自己接受本站规则且自行承担风险,本站不退款、不进行额外附加服务;查看《如何避免下载的几个坑》。如果您已付费下载过本站文档,您可以点击 这里二次下载。
- 4、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等,请点击“版权申诉”(推荐),也可以打举报电话:400-050-0827(电话支持时间:9:00-18:30)。
查看更多
有机材料的封装
Entrapment of Organic Molecules
GENERAL ASPECTS OF ENCAPSULATION OF ORGANIC MOLECULES IN SOL–GEL GLASSES
The sol–gel process is a chemical synthesis technique for preparing inorganic oxides at low temperature such as ambient temperature. This mild condition enables one to form organic molecule-doped inorganic materials that cannot be obtained by the conventional high temperature processes. The basic idea is simple, but the impact is very vast. Therefore, doping glasses with organic molecules has become one of the most important fields of the sol–gel process (Avnir, 1992, 1995). The process is as follows: adding the desired dopant to the starting sol–gel solutions, gelation, and drying. In general, organic dopant molecules are dissolved in methanol, ethanol or water. The dopants are introduced into the sol–gel systems by adding solutions. The first example was rhodamine 6G in tetramethoxysilane (TMOS)-derived silica (Avnir, 1984). Since then encapsulation of organic molecules in sol–gel glasses has extended in various fields such as photonic materials (Zink, 1991; Reisfeld, 1996), sensors (Wolbeis, 1996), organic/inorganic hybrids (Coltrain, 1996), template synthesis of organized matter (Mann, 1997), biochemical–inorganic composites (Avnir, 1994; Premkumar, 2002) and so on.
Some of the properties and advantages of the doped sol–gel glasses were summarized as follows (Avnir, 1992):
The glasses are stable thermally, chemically and photochemically, especially when compared to plastics matrices.
The encapsulated molecules are well protected much better than in plastics.
The glasses are transparent well into the UV, allowing a whole array of photochemical, photophysical and optical applications.
The trapped molecules are either non-leachable, or, in some cases, leachable over a very long time period.
A sub-population of the non-leachable molecules is trapped close enough to the pore-surface, to be able to interact with substrate molecules contained in the pore-surface.
Th
您可能关注的文档
- 最新版PEP人教版六年级英语下册Unit4Then and now 复习课件.ppt
- 最新版QA 品质保证系统.ppt
- 最新外研版英语七年级下册module8-story-time.ppt
- 最新最全H3C_VISIO_图库.ppt
- 最新PPT模板.ppt
- 最新山东教育出版社六年级下课件unit7 Section A 2.ppt
- 最新外研版英语七年级下册module8_story_time.ppt
- 最新版外研版九年级上英语课文M1-6.doc
- 最新版深圳七年级下册英语课文与翻译.doc
- 最新版PEP人教版六年级英语下册Unit4Then-and-now-复习课件.ppt
- 劳保用品管理制度.docx
- 施工设施设备和劳动防护用品安全管理制度.docx
- 2024年山东省青岛市市北区部分事业单位招聘23人历年高频考题难、易错点模拟试题(共500题)附带答案详解.docx
- 2024年山东省济宁市兖州区事业单位急需紧缺高层次人才引进29人历年高频考题难、易错点模拟试题(共500题)附带答案详解.docx
- 2024年山东高速高新科技投资限公司校园招聘高频考题难、易错点模拟试题(共500题)附带答案详解.docx
- 2024年山东省济南市钢城区事业单位招聘58人历年高频考题难、易错点模拟试题(共500题)附带答案详解.docx
- 2024年山东省济宁微山县事业单位公开招聘工作人员(综合类)185人历年高频考题难、易错点模拟试题(共500题)附带答案详解.docx
- 2024年山东省烟台龙口市事业单位招聘急需紧缺人才27人历年高频考题难、易错点模拟试题(共500题)附带答案详解.docx
- 2024年山西太原大中专毕业生就业指导中心招聘5人历年高频考题难、易错点模拟试题(共500题)附带答案详解.docx
- 2024年山东省聊城东阿县事业单位选聘32人历年高频考题难、易错点模拟试题(共500题)附带答案详解.docx
文档评论(0)