nacl 改性沸石对水中氨氮的吸附机制.pdf

中国环境科学 2016,36(12) ：3567~3575 China Environmental Science NaCl 改性沸石对水中氨氮的吸附机制 * 李文静,李 军 ,张彦灼,程笑婕,卞 伟 (北京工业大学建筑工程学院,北京市水质科学与水环境恢复工程北 京市重点实验室,北京 100124) 摘要：通过颗粒强度测定、扫描电镜分析(SEM)、X 射线能谱分析(EDS)和零电点测定(pHPZC)考察改性前后沸石表面特性的变化,考察 pH 值、沸石投加量、初始氨氮浓度以及温度对吸附过程的影响,并通过吸附等温式和吸附动力学对吸附机制进行描述.经过 NaCl 改性后的沸 石的颗粒强度明显增大,表面更加粗糙,孔径增大,钠离子通过交换作用进入到沸石内部.pH 值为 7,沸石投加量为 8g/L,温度为 35℃时吸附效 果最好,平衡吸附量(q ) 与氨氮初始浓度呈正相关性.Langmuir 等温线比 Freundlich 等温线更适合描述实验数据,最大饱和吸附量为 e 13.210mg/g.吸附动力学符合准二级动力学模型.实验表明NaCl 改性沸石能够有效去除水中的氨氮. 关键词：NaCl ；改性；沸石；吸附；氨氮 中图分类号：X703.1 文献标识码：A 文章编号：1000-6923(2016)12-3567-09 * Adsorption mechanism of ammonium from aqueous solutions by NaCl modified zeolite. LI Wen-jing, LI Jun , ZHANG Yan-zhuo, CHENG Xiao-jie, BIAN Wei (College of Architecture and Civil Engineering, Key Laboratory of Beijing for Water Quality Science Water Environment Recovery Engineering, Beijing University of Technology, Beijing 100124, China). China Environmental Science, 2016,36(12)：3567~3575 Abstract ：Surface morphology of zeolite before and after modified was analyzed through the particle strength, scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS) and point of zero charge (pHPZC). Adsorption studies were carried out at different pH, zeolite dosage, initial ammonium concentrations and temperature. Adsorption mechanism was measured through the adsorption isotherm and adsorption dynamics. The feature of NaCl modified zeolite included increased particle strength, a rough surface, and enlarged pore size. It was also found that sodium ions would enter t