浙江大学化学系有机合成化学OS2-1.pptVIP

Oxidation Oxidation in organic chemistry refers to either the elimination of hydrogen or the replacement of a hydrogen atom bonded to carbon with another more electronegative element. Alcohols to carbonyls Conversion of alkenes to epoxides Conversion of alkenes to diols Oxidation bond cleavage Oxidation of alkyl or alkenyl fragments Bayer-Villiger oxidation Oxidation of other element Alcohols to carbonyls 1.1 Oxidation with chronium (VI) 1.2 Dimethyl sulfoxide 1.3 Other metal oxidants 1.4 Other oxidation regents 1.1 Oxidation with chronium (VI) Example Chromium trioxide-pyridine: Sarre